The first comprehensive study of electron gains and losses in hypersonic air flows including the full coupling between the non-neutral plasma sheaths and the quasi-neutral plasma flow is here presented. Such is made possible by the use of advanced numerical methods that overcome the stiffness associated with the plasma sheaths. The coupling between the sheaths, the electron temperature in non-equilibrium, and the ambipolar diffusion within the quasi-neutral plasma flow is found to be critical to predict accurately electron losses and, thus, plasma density around hypersonic vehicles. This is because electron cooling coming from the non-neutral sheaths affects significantly electron temperature everywhere in the plasma and, therefore, the electron-temperature-dependent loss processes of ambipolar diffusion and dissociative recombination. Results obtained show that electron loss to the surface due to catalyticity dominates over electron loss within the plasma due to dissociative recombination either (i) at high altitude where the dynamic pressure is low, or (ii) at low Mach number, or (iii) when the vehicle has a sharp leading edge.