This paper addresses the analysis, validation, and application of analytic, nonperturbative, semiclassical vibration -translation (V -T ) and vibration -vibration -translation (V -V -T ) rate models for atom -diatom and diatom -diatom vibrational molecular energy transfer collisions. These forced harmonic oscillator (FHO ) rate models are corrected and validated by comparison with recent experiments, and with three-dimensional semiclassical trajectory calculations for N 2 -N 2 , O 2 -O 2 , and N 2 -O 2 , which are considered to be the most reliable theoretical data available. A remarkably good overall agreement is shown for both the temperature and quantum number dependence of single-quantum and double-quantum V -V -T transitions in the temperature range 200 # T # 8000 K and for vibrational quantum numbers 0 # v # 40. It is demonstrated that the multiquantum vibrational energy transfer processes occur via a sequential FHO mechanism, as a series of virtual single-quantum steps during one collision. An important exception, asymmetric multiquantum V -V exchange at low temperatures, that occurs via a direct rstorder mechanism, is discussed. Analytic thermally averaged FHO V -T and V -V rates are suggested. The FHO model gives new insight into vibrational kinetics and may be easily incorporated into kinetic modeling calculations under conditions when rst-order theories are not applicable.

Direct measurements of the dielectric surface potential and its dynamics in asymmetric dielectric barrier discharge (DBD) plasma actuators show that the charge builds up at the dielectric surface and extends far downstream of the plasma. The surface charge persists for a long time (tens of minutes) after the driving voltage has been turned off. For a sinusoidal voltage waveform, the dielectric surface charges positively. With the voltage waveform consisting of nanosecond pulses superimposed on a dc bias, the sign of the dielectric surface charge is the same as the sign (polarity) of the bias voltage. The surface charging significantly affects DBD plasma actuator performance.

Experimental studies were conducted of a flow induced in an initially quiescent room air by a single asymmetric dielectric barrier discharge driven by voltage waveforms consisting of repetitive nanosecond high-voltage pulses superimposed on dc or alternating sinusoidal or square-wave bias voltage. To characterize the pulses and to optimize their matching to the plasma, a numerical code for short pulse calculations with an arbitrary impedance load was developed. A new approach for nonintrusive diagnostics of plasma actuator induced flows in quiescent gas was proposed, consisting of three elements coupled together: the schlieren technique, burst mode of plasma actuator operation, and two-dimensional numerical fluid modeling. The force and heating rate calculated by a plasma model was used as an input to two-dimensional viscous flow solver to predict the time-dependent dielectric barrier discharge induced flow field. This approach allowed us to restore the entire two-dimensional unsteady plasma induced flow pattern as well as characteristics of the plasma induced force. Both the experiments and computations showed the same vortex flow structures induced by the actuator. Parametric studies of the vortices at different bias voltages, pulse polarities, peak pulse voltages, and pulse repetition rates were conducted experimentally. The significance of charge buildup on the dielectric surface was demonstrated. The charge buildup decreases the effective electric field in the plasma and reduces the plasma actuator performance. The accumulated surface charge can be removed by switching the bias polarity, which leads to a newly proposed voltage waveform consisting of high-voltage nanosecond repetitive pulses superimposed on a high-voltage low frequency sinusoidal voltage. Advantages of the new voltage waveform were demonstrated experimentally.

No abstract

A detailed physical model for asymmetric dielectric barrier discharge (DBD) in air at low voltages (1.5–2 kV) is developed. Modeling of DBD with an applied sinusoidal voltage is carried out in two dimensions. The leading role of charging the dielectric surface by electrons in the cathode phase is shown to be critical, acting as a harpoon that pulls positive ions forward and accelerates the gas in the anode phase. The positive ion motion back toward the exposed electrode is shown to be a major source of inefficiency in the sinusoidal or near-sinusoidal voltage cases. Based on understanding of the DBD physics, an optimal voltage waveform is proposed, consisting of high repetition rate, short (a few nanoseconds in duration), negative pulses combined with a positive dc bias applied to the exposed electrode.