1994
DOI: 10.1021/j100059a036
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Oblique Infrared Transmission Spectroscopic Study on the E .fwdarw. C and B .fwdarw. C Phase Transitions of Stearic Acid: Effects of Polytypic Structure

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Cited by 27 publications
(23 citation statements)
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“…A similar state of the resultant crystals was observed in the E f C transition of stearic acid. 19,20 We have confirmed with oblique IR transmission method 20 that the LM(Orth II) phase transforms to the HM phase of the single-layered structure. The obtuse bisectrix (//b s ) of a singlecrystal specimen was set parallel to the electric vector of the incident radiation, and the crystal was rotated around the acute bisectrix (//a s ).…”
Section: Crystallization Process Of the Lm Phasementioning
confidence: 64%
“…A similar state of the resultant crystals was observed in the E f C transition of stearic acid. 19,20 We have confirmed with oblique IR transmission method 20 that the LM(Orth II) phase transforms to the HM phase of the single-layered structure. The obtuse bisectrix (//b s ) of a singlecrystal specimen was set parallel to the electric vector of the incident radiation, and the crystal was rotated around the acute bisectrix (//a s ).…”
Section: Crystallization Process Of the Lm Phasementioning
confidence: 64%
“…Therefore, we infer that the unchanged intensities of the b s -components shown in Figure 6b are ascribed to such an inclination behavior that the b s -axis inclines toward the opposite directions alternately along the successive layer ( Figure 6d). 15 In this type of stacking mode, the b s -components of δ(CH 2 ) and r(CH 2 ) due to the A-leaflet become weak at φ ) +30°, while they increase at φ ) -30°. On the other hand, the b s -components due to the B-leaflet increase in intensity at φ ) +30°, while they decrease at φ ) -30°.…”
Section: Resultsmentioning
confidence: 97%
“…6b). It has been reported that stearic acid is crystallized from acetone as C-form [39], which is categorized in monoclinic crystal [40]. …”
Section: Resultsmentioning
confidence: 99%