Plasma wakefield accelerators use tabletop equipment to produce relativistic femtosecond electron bunches. Optical and x-ray diagnostics have established that their charge concentrates within a micrometer-sized volume, but its sub-micrometer internal distribution, which critically influences gain in free-electron lasers or particle yield in colliders, has proven elusive to characterize. Here, by simultaneously imaging different
wavelengths of coherent optical transition radiation (COTR) that
a laser-wakefield-accelerated e-bunch generated when exiting a metal foil, we elucidated the structure of the coherently-radiating component of bunch charge. Key features of the images correlated uniquely with how plasma electrons injected into the wake: by a plasma-density discontinuity, by ionising high-Z gas-target dopants, or by uncontrolled laser-plasma dynamics. With additional input from electron spectra, spatially-averaged COTR spectra, and particle-in-cell simulations, we reconstructed coherent 3D charge structures. The results demonstrate
essential metrology for next-generation X-ray free-electron lasers.