Octachloro- and Hexadecafluoro-Substituted Lanthanide(III) Phthalocyaninates: Synthesis and Spectral Properties

Kuzmina, E. A.; Dubinina, Tatiana V.; Borisova, Nataliya E.; Tomilova, Larisa G.

doi:10.6060/mhc171253d

Cited by 12 publications

(1 citation statement)

References 30 publications

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“…Microwaveassisted synthesis has successfully provided macrocycles functionalized with halides, [41][42][43][44] terminal alkynes, [45] crown ethers, [46] substituted phenoxy [47][48][49] and 1-naphthyloxy [50] groups, tetraaza, [51] tetraoxamonoaza, [52] tetrathiacyclohexadecane, [53] dithiadiazadioxa, [54] diazadithio [55] and tetrathiadiaza rings, [56,57] thiazoles, [58] functionalized triazoles, [59][60][61][62] phenylthioethanol, [63] monoterpenes like (1R)-(À ) myrtenol and (1R,2S,5R)-(À )menthol, [64] benzenesulfonamide, [65] pyridine [66] and azo compounds. [67] Microwaves have been also employed to synthesize silicon [68] lanthanide(III), [69] lead, [49,70] and platinum [71] derivatives, and phthalocyanine-based polymers. [72][73][74] Kantar et al used the microwave-assisted approach for the tetramerization of phthalonitriles bearing different substituents at positions 4-and 5-.…”

Section: Microwave Irradiationmentioning

confidence: 99%

Phthalocyanines Synthesis: A State‐of‐The‐Art Review of Sustainable Approaches Through Green Chemistry Metrics

Zanotti,

Palmeri,

Raglione

2024

Chemistry A European J

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Driven by escalating environmental concerns, synthetic chemistry faces an urgent need for a green revolution. Green chemistry, with its focus on low environmental impacting chemicals and minimized waste production, emerges as a powerful tool in addressing this challenge. Metrics such as the E‐factor guide the design of environmentally friendly strategies for chemical processes by quantifying the waste generated in obtaining target products, thus enabling interventions to minimize it. Phthalocyanines (Pcs), versatile molecules with exceptional physical and chemical properties, hold immense potential for technological applications. This review aims to bridge the gap between green chemistry and phthalocyanine synthesis by collecting the main examples of environmentally sustainable syntheses documented in the literature. The calculation of the E‐factor of a selection of them provides insights on how crucial it is to evaluate a synthetic process in its entirety. This approach allows for a better evaluation of the actual sustainability of the phthalocyanine synthetic process and indicates possible strategies to improve it.

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Section: Microwave Irradiationmentioning

confidence: 99%

Phthalocyanines Synthesis: A State‐of‐The‐Art Review of Sustainable Approaches Through Green Chemistry Metrics

Zanotti,

Palmeri,

Raglione

2024

Chemistry A European J

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Microwave-assisted synthesis of macroheterocyclic compounds using 1-alkyl-1,2,4-triazoles

2018

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Planar and sandwich-type Pr(III) and Nd(III) chlorinated phthalocyaninates: Synthesis, thermal stability and optical properties

et al. 2020

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Octachloro- and Hexadecafluoro-Substituted Lanthanide(III) Phthalocyaninates: Synthesis and Spectral Properties

Abstract: Octachloro-and hexadecafluoro-substituted lanthanide(III) monophthalocyaninates

Cited by 12 publications

References 30 publications

Phthalocyanines Synthesis: A State‐of‐The‐Art Review of Sustainable Approaches Through Green Chemistry Metrics

Phthalocyanines Synthesis: A State‐of‐The‐Art Review of Sustainable Approaches Through Green Chemistry Metrics

Microwave-assisted synthesis of macroheterocyclic compounds using 1-alkyl-1,2,4-triazoles

Planar and sandwich-type Pr(III) and Nd(III) chlorinated phthalocyaninates: Synthesis, thermal stability and optical properties

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