A highly soluble and polymerizable derivative of 9,10-diphenylanthracene was designed and synthesized specifically to be capable of achieving very high loadings (at least 50 wt.%) when copolymerized with a polyvinyltoluene (PVT) matrix. The resulting heavily crosslinked plastics are mechanically hard and robust, and were found to have exceptional clarity with no sign of dye precipitation. Samples of these plastics both with and without added wavelength shifter were characterized for light yield, scintillation decay, and pulse shape discrimination (PSD) performance for α/γ discrimination, and the results were compared to that of a commercially available PSD plastic, EJ-299-34. The best performing formulation, with a primary dye loading of 50 wt.%, had a measured light yield of 9950 photons/MeV, and achieved a PSD figure-of-merit (FOM) of 1.05, the latter indicating that while the present material is not suited for practical applications, the overall approach demonstrates a proof-of-concept of PSD in highly loaded plastics stabilized through copolymerization of the primary dye, and suggests that further improvements through better dye choice/design may yet be achievable.The variation in pulse shape originating from excitation from different high-energy 2 particles is the origin of the technique of pulse shape discrimination (PSD), a tech-3 nique that can be used to actively identify the type of the detected particle. In contrast 4 to inorganic scintillators, which are among the best materials for γ-ray detection and 5 spectroscopy, organic materials are among the most widely used materials for PSD ap-6 plications [1], a primary example of which is the use of PSD based detection methods 7 for fast-n/γ discrimination, which is of particular interest for the detection of special 8 nuclear material (SNM). The PSD properties of organic scintillators have a long his-9 tory dating back to the 1950's [2]. Organic crystals are among the highest performing 10 materials for n/γ PSD, with single crystal trans-stilbene being readily considered as 11 having the best known PSD performance [2, 3]. On the other hand, PSD is readily 12 achievable in conventional liquid scintillator solutions, which have distinct advantage 13 over organic crystals in terms of cost, scalability, and ease of manufacture and han-14 dling. There are some distinct disadvantages of organic liquids, including concerns 15 over toxicity, flammability, the potential for leaks, and the necessity of maintaining 16 strict oxygen free conditions of the solution throughout its life, all of which are even 17 more problematic in the context of very large detector sizes. Despite these shortcom-18 ings, liquid scintillator solutions are among the most widely used detector materials for 19 fast neutron spectroscopy and n/γ discrimination.
20For other types of detection, plastic scintillators offer many distinct advantages over 21 organic or even inorganic crystals and liquid scintillator solutions, most notably low 22 cost, very good scalability, and great ease of use a...