We have fabricated erbium-doped amorphous silicon p-i-n structures by conventional plasma decomposition of silane. The erbium doping was achieved by sublimation of the metal-organic compound tris(2,4-pentanedionato)-Er(III) which has a more favorable erbium-carbon ratio than previously used compounds. Since the Er centers introduce donors and defects in the amorphous silicon, counterdoping with diborane has been required to obtain the near-intrinsic i layers with a reduced defect density. The p-i-n junctions have excellent diode characteristics and exhibit, under forward bias, pronounced electroluminescence near 1.54 µm at room temperature. Their power efficiency is by two orders of magnitude larger than that of previously fabricated heterojunctions of amorphous and crystalline silicon. We discuss possible mechanisms of the Er 3+ excitation in our diodes.