It is very well known that a sequence of polynomials {Q n (x)} ∞ n=0 orthogonal with respect to a Sobolev discrete inner productwhere µ is a finite Borel measure and I is an interval of the real line, satisfies a five-term recurrence relation.In this contribution we study other three families of polynomials which are linearly independent solutions of such a five term linear difference equation and, as a consequence, we obtain a polynomial basis of such a linear space. They constitute the analog of the associated polynomials in the standard case. Their explicit expression in terms of {Q n (x)} ∞ n=0 using an integral representation is given. Finally, an application of these polynomials in rational approximation is shown.