We consider the Cauchy problem for the nonlinear Schrödinger equations (NLS) with non-algebraic nonlinearities on the Euclidean space. In particular, we study the energy-critical NLS on R d , d = 5, 6, and energy-critical NLS without gauge invariance and prove that they are almost surely locally well-posed with respect to randomized initial data below the energy space. We also study the long time behavior of solutions to these equations: (i) we prove almost sure global well-posedness of the (standard) energy-critical NLS on R d , d = 5, 6, in the defocusing case, and (ii) we present a probabilistic construction of finite time blowup solutions to the energy-critical NLS without gauge invariance below the energy space. Contents 2010 Mathematics Subject Classification. 35Q55. Key words and phrases. nonlinear Schrödinger equation; almost sure local well-posedness; almost sure global well-posedness; finite time blowup. c T γ φ 2 H s such that for each ω ∈ Ω T , there exists a unique solution, where S(t) = e it∆ and X 1 T is defined in Section 3 below. Almost sure local well-posedness with respect to the Wiener randomization has been studied in the context of the cubic NLS and the quintic NLS on R d [2, 3, 8] which are energy-critical in dimensions 4 and 3, respectively. Note that when d = 5, 6, the energycritical nonlinearity |u| 4 d−2 u is no longer algebraic, presenting a new difficulty in applying the argument in [2,3,8].