2018
DOI: 10.1021/acs.jpcb.8b10638
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On the Mesoscale Solubility in Liquid Solutions and Mixtures

Abstract: We report on a mesoscale solubility reflecting the fact that solubility is achieved not only by the well-known "like likes like" or "like dissolves like" based on molecular solvation but also on mesoscale solubilization of dislike compounds characterized in that the solubility (homogeneous distribution over the whole volume of the system) is achieved on a mesoscale level ranging from tens to hundreds of nanometers. It is shown that mesoscale solubility is a spontaneously occurring, literally everywhere present… Show more

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Cited by 39 publications
(65 citation statements)
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References 33 publications
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“…4951 Small-angle neutron and dynamic light scattering experiments detect short-lived (<50 ps), short-ranged (∼1 nm) concentration fluctuations in most water–hydrotrope mixtures such as the W:AN system. 5052 In the presence of hydrophobic solutes, such as β-C in our experiments, such fluctuations are stabilized and extend into persistent, mesoscopic (10–100 nm) inhomogeneities. 5355 The message is that the existence of nanometer-level inhomogeneities in all “internally mixed” solutions is a general phenomenon that could play hitherto unrecognized roles in atmospheric aqueous media.…”
mentioning
confidence: 58%
“…4951 Small-angle neutron and dynamic light scattering experiments detect short-lived (<50 ps), short-ranged (∼1 nm) concentration fluctuations in most water–hydrotrope mixtures such as the W:AN system. 5052 In the presence of hydrophobic solutes, such as β-C in our experiments, such fluctuations are stabilized and extend into persistent, mesoscopic (10–100 nm) inhomogeneities. 5355 The message is that the existence of nanometer-level inhomogeneities in all “internally mixed” solutions is a general phenomenon that could play hitherto unrecognized roles in atmospheric aqueous media.…”
mentioning
confidence: 58%
“…These domains are generally present in mixtures of water with miscible organic solvents. [57][58][59] This is substantiated by small-angle neutron and dynamic light scattering experiments detect short-lived (< 50 ps), short-ranged (1 nm) concentration fluctuations in most water-hydrotrope mixtures, [58][59][60] and with recent reactivity and selectivity studies of reactions in these media. 57, A recent soft X-ray absorption spectroscopic study of W:AN mixtures presented evidence of microheterogeneity.…”
Section: Table 1-rate Coefficients Of -Hhs Decay In Water:acetonitrimentioning
confidence: 71%
“…Linalool exhibits a higher diffusivity in diluted solutions than that of 1-decanol and a higher dynamic and equilibrium interfacial activity as compared to benzyl alcohol, resulting in 100 times lower amount of linalool to produce the same interfacial effect as benzyl alcohol (Table S2). We note that measurements of the surface tension of solutions of poorly soluble aroma molecules are complicated by so called mesoscale solubility of organic liquids in water . During tensiometric measurements, the mesoscale solubility in a form of “heterogeneous” oil droplets has to be taken into account.…”
Section: Resultsmentioning
confidence: 99%