2017
DOI: 10.1017/s1743921317007414
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On the origin of O2 and other volatile species in comets

Abstract: Abstract. Molecular oxygen, O2, was recently detected in comet 67P by the ROSINA instrument on board the Rosetta spacecraft with a surprisingly high abundance of 4% relative to H2O, making O2 the fourth most abundant in comet 67P. Other volatile species with similar volatility, such as molecular nitrogen N2, were also detected by Rosetta, but with much lower abundances and much weaker correlations with water. Here, we investigate the chemical and physical origin of O2 and other volatile species using the new c… Show more

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Cited by 5 publications
(8 citation statements)
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“…-Similar conclusions arise from the abundant amounts of O 2 , which were well correlated to H 2 O in 67P/C-G (Bieler et al 2015a). O 2 has a presolar or molecular cloud origin and formed either through cold temperature chemistry (Taquet et al 2017) and/or radiolysis (Mousis et al 2016b). Chemical formation requires slightly increased formation temperatures (∼20 K) and gas densities (n H 10 5 cm −3 ), similar to the case of the dense core ρ Ophiuchus A, but warmer compared to the lower mass environment expected for the early Sun.…”
Section: Discussionsupporting
confidence: 55%
“…-Similar conclusions arise from the abundant amounts of O 2 , which were well correlated to H 2 O in 67P/C-G (Bieler et al 2015a). O 2 has a presolar or molecular cloud origin and formed either through cold temperature chemistry (Taquet et al 2017) and/or radiolysis (Mousis et al 2016b). Chemical formation requires slightly increased formation temperatures (∼20 K) and gas densities (n H 10 5 cm −3 ), similar to the case of the dense core ρ Ophiuchus A, but warmer compared to the lower mass environment expected for the early Sun.…”
Section: Discussionsupporting
confidence: 55%
“…This detection opens new scenarios and raises interest in the possibility of detecting molecular oxygen in cometary and interstellar ice. Recent work by Taquet et al (2016) show that solid O 2 , with a molecular ratio to water ice similar to those measured in comet 67P, can be produced in molecular clouds with relatively low H to O abundance ratio in the gas phase, high densities (≥10 5 cm −3 ) and dust temperature around 20 K, higher than that typically measured in interstellar dark clouds (10-15 K).…”
Section: Introductionmentioning
confidence: 65%
“…The preservation of the inner layers of the icy grain mantles from the dark cloud stage until their incorporation into cometary nuclei is supported by the observation of a distributed source of halogens in the coma of 67P/C-G (Dhooghe et al 2017). Thus, the scenario of O 2 production and the subsequent evolution of ice during the transition from dark cloud to protoplanetary disk discussed in Taquet et al (2016) and Taquet et al (2017) is consistent with observations of other volatiles (such as N 2 and CO) made at 67P/C-G.…”
Section: Recombination Of Oxygen Atoms On the Surfaces Of Interstellamentioning
confidence: 77%
“…Contrary to O 2 , CO and N 2 mostly form in the outermost layers of the icy mantle. Taquet et al (2017) detail the impact of layering of the icy mantle during the transition from dark cloud to protoplanetary disk and its consequences to the volatile content of cometary ices. The outer layers of the icy grains are more likely to evaporate in the outer layer of the protoplanetary disk releasing N 2 and CO in the gas phase, while the inner ice layers where most of the O 2 would be trapped remains frozen.…”
Section: Recombination Of Oxygen Atoms On the Surfaces Of Interstellamentioning
confidence: 99%