Key words anisotropic materials, isotropic functions, structural tensors MSC (2000) 15A72, 74E10We demonstrate that any number of vectors and second order tensors can merely characterize and represent one of the cylindrical groups and the triclinic, monoclinic, rhombic crystal classes. This suggests that, for anisotropic functions relative to any anisotropic material symmetry group other than those just mentioned, the widely used isotropic extension method via structural tensors has to result in isotropic extension functions involving at least one structural tensor variable of order higher than two. The latter do not fall within the scope of the conventional isotropic functions of vector variables and second-order tensor variables. In addition to the trivial case of the lowest material symmetry represented by the triclinic groups, isotropic extension functions in conventional sense would be possible only for a few limited cases, including transversely isotropic, orthotropic, monotropic functions, etc. 234 321 4229 1 Extensive results have been derived in the restrictive case of polynomial representation for various kinds of crystal symmetry and transverse isotropy, mainly for scalar-valued functions, and summarized in, e.g., [16] and [15]. A general case is concerned with the representative problem of both polynomial and non-polynomial scalar-and tensor-valued functions. Our discussion is intended for this general case.