Signal analysis of Galileo images of the Moon suggests the presence of an absorption band centered near 0.7 μm in the reflectance spectra of areas located adjacent to the equatorward walls of lunar craters at latitudes ranging from −58 to −78• , and areas contained in the South Pole-Aitken Basin. We propose three potential explanations: an Fe 2+ →Fe 3+ charge transfer transition in oxidized iron in clinopyroxenes (high-Ca bearing pyroxenes) or phyllosilicates (Fe-and Mg-bearing sheet silicates containing adsorbed H 2 O and interlayer OH − ), or an effect of titanium in ilmenite (a common lunar opaque material). No identification of the mineralogy is conclusive. The presence and nature of the absorption feature could be confirmed using AMICA images of the lunar far side from the Japanese mission Hayabusa, spectroscopic results from the Japanese mission Selene scheduled for launch in 2007, or the Moon Mineralology Mapper on the Indian mission Chandrayaan-1. Key words: Moon, lunar surface composition, spectral reflectance, lunar mineralogy, lunar remote sensing.
Motivation and Background for Search for Lunar PhyllosilicatesSpectral observations of reflected sunlight from the surface of a planetary regolith serve as a remote sensing probe of surface mineralogical composition and particle state. Variations from the solar spectrum in the spectrum of a planetary regolith, apparent in the form of broad absorption features, reflect the presence of electronic charge transfers and vibrations between ions governed by structural spacing within crystals of a specific mineralogy (c.f., Burns, 1993). By identifying and analyzing these spectral variations, the underlying mineralogy of the planetary regolith can be determined. The identification of different minerals provides clues to the processes that formed or altered these solar system bodies. On the Moon, regolith particles of diameters ≤25 μm dominate the remotely-sensed spectral properties of the surface over the visible/near-infrared wavelength region (Pieters et al., 1993a).Water ice has long been postulated to exist in permanently shaded areas at the lunar poles (c.f., Watson et al., 1961;Arnold, 1979). Recent observations provide conflicting evidence for the presence and form of lunar polar water ice. Clementine bistatic radar detected a weak sig- * Present address: MMT Observatory, P.O. Box 210065, University of Arizona, Tucson, Arizona 85721. nal at the lunar South pole attributed to water ice (Nozette et al., 1996), while Lunar Prospector has recently detected large amounts of H at both poles (Feldman et al., 2000(Feldman et al., , 2001. Conversely, ground-based radar searches show no bright signal suggesting water ice at either pole (Stacy et al., 1997), andCampbell et al. (2006) find no evidence of thick deposits of ice at the South pole. Reanalysis of the Clementine radar data by Simpson and Tyler (1999) suggest that the radar reflection results were caused by underlying variations in terrain. Galileo near-infrared spectra detected no sign of the prominent 3.0-μm...