On the Temperature Dependence of Radiationless Electron Transitions. II. The Morse Oscillator Model in case of an “Arbitrary” Parameter Z

Kovalev, A. A.; Makshantsev, B. I.

doi:10.1080/00387017208064680

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“…For example the Franck-Condon factor, which is in fact the overlap of the vibrational wave function in two different electronic states and which controls the transition rate of the radiationless transitions, can, in principle, be calculated using a harmonic approximation. However, the neglect of anharmonicity for highly excited vibrational states may underestimate the transition rate by many orders of magnitude as demonstrated in reference [4], where the Franck -Condon factor was calculated for Morse oscillators.…”

Section: Introductionmentioning

confidence: 99%