On the thermal decomposition of the zinc(II) hydroxide chlorides Zn5(OH)8Cl2�H2O and ?-Zn(OH)Cl

García-Martínez, O.; Vila, E.; Vidales, J. L. Martı́n de; Rojas, R.M.; Petrov, Κ.

doi:10.1007/bf01171557

Cited by 48 publications

(37 citation statements)

References 7 publications

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“…At the same time, the ZnO phase appeared at around 180 1C. The formation of b-Zn(OH)Cl during the decomposition of ZHC has been reported before [20,21]. It is interesting that b-Zn(OH)Cl with the high intensity of (003) reflection show high c-axis orientation.…”

Section: Thermal Analysismentioning

confidence: 86%

“…The corresponding XRD patterns indicated that the first sharp exothermic peak (T max ¼208.3 1C) and second broad exothermic peak between 65 and 55 1C (T max ¼59.6 1C) corresponds to the regeneration of b-Zn(OH)Cl (green XRD pattern) and ZHC (blue XRD pattern), respectively. The regeneration of b-Zn(OH)Cl suggests the residual presence of ZnCl 2 in the formed ZnO and its regeneration mechanism has been proposed by Garcia-Martinez et al [20]:…”

Section: Thermal Decomposition Of Zhcmentioning

confidence: 96%

“…5d) indicated that the additional weight loss was occurred at higher temperatures after the formation of the ZnO single-phase. GarciaMartinez et al [20] indicated the presence of residual amorphous ZnCl 2 in the formed ZnO. To clarify the role of residual ZnCl 2 , reversed thermal analysis of the ZHC was conducted by heating pattern (B) (see Section 2).…”

Section: Thermal Decomposition Of Zhcmentioning

confidence: 99%

“…The thermal decomposition process of ZHC has been reported by Garcia-Martinez et al [20] and other researchers [21,22]. Garcia-Martinez et al [20] investigated the thermal decomposition process of ZHC in terms of a heating rate.…”

Section: Introductionmentioning

confidence: 95%

“…Garcia-Martinez et al [20] investigated the thermal decomposition process of ZHC in terms of a heating rate. As shown by Arii and Kishi [19], the presence of water vapor in the atmosphere may also affect the thermal decomposition process of ZHC.…”

Section: Introductionmentioning

confidence: 99%

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Effect of water vapor on the thermal decomposition process of zinc hydroxide chloride and crystal growth of zinc oxide

Kozawa

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Section: Thermal Analysismentioning

confidence: 86%

Section: Thermal Decomposition Of Zhcmentioning

confidence: 96%

Section: Thermal Decomposition Of Zhcmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 95%

Section: Introductionmentioning

confidence: 99%

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Effect of water vapor on the thermal decomposition process of zinc hydroxide chloride and crystal growth of zinc oxide

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Yanagisawa

et al. 2011

Journal of Solid State Chemistry

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A General Route to Printable High‐Mobility Transparent Amorphous Oxide Semiconductors

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Inkjet printing of inorganic materials for the formation of active devices is relatively rare compared to the research done with respect to organic materials. To date, only a handful of inorganic materials have been ink-jet printed, primarily because of the difficulty in preparing ink-jet-printable precursors. We have developed a general and low-cost route to the ink-jet printing of transparent amorphous oxide semiconductors. Our process uses metal halide precursors dissolved in acetonitrile, an organic solvent. This precursor solution is capable of forming a uniform and continuous metal halide thin film over a large area through both ink-jet printing and blanket-coating techniques. The printed metal halide thin films are converted to semiconducting metal oxides by thermally annealing the metal halides in the air. In this paper, we report thin-film transistors (TFTs) that were fabricated using this technique with field-effect mobilities as high as 7.4 cm 2 V -1 s -1 and 16.1 cm 2 V -1 s -1

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Unveiling Charge Transport and Degradation Mechanisms of Aqueous Zn|α‐MoO₃ Batteries in Conventional Concentration and Water‐in‐Salt Electrolytes: A Multi‐Modal In Situ and Operando Study

Dunkin

Kuang

Yan

et al. 2022

Adv Materials Inter

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Herein charge storage and transport properties are elucidated and cell degradation mechanisms of rechargeable aqueous Zn|α‐MoO3 batteries in three electrolyte systems (3 m ZnSO4, 3 m ZnCl2, and 30 m ZnCl2 [12.5 m] water‐in‐salt (WIS)) are distinguished by a combination of in situ X‐ray diffraction (XRD), in situ X‐ray absorption spectroscopy (XAS), operando optoelectrochemistry, and operando energy dispersive X‐ray diffraction (EDXRD). In conventional concentration 3 m electrolytes, in situ XRD and XAS, as well as ex situ scanning transmission electron microscopy data collectively support Zn2+ as the primary charge carrier. In addition, these systems are susceptible to cathode dissolution, Zn corrosion coupled with the hydrogen evolution reaction, and the resultant formation of basic zinc salt phases. The multi‐modal in situ and operando experimental analyses validate facile H+ intercalation and extraction in concentrated 30 m ZnCl2 WIS electrolyte. Via operando EDXRD, reaction front and charge transport limitation during discharge and charge in the viscous WIS electrolyte are spatially tracked. This work provides new insight into the stability and degradation mechanisms of aqueous zinc batteries during static storage and upon dynamic cycling, and highlights the utility of in situ and operando techniques in understanding the superior stability of WIS electrolytes.

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On the thermal decomposition of the zinc(II) hydroxide chlorides Zn5(OH)8Cl2�H2O and ?-Zn(OH)Cl

Cited by 48 publications

References 7 publications

Effect of water vapor on the thermal decomposition process of zinc hydroxide chloride and crystal growth of zinc oxide

Effect of water vapor on the thermal decomposition process of zinc hydroxide chloride and crystal growth of zinc oxide

A General Route to Printable High‐Mobility Transparent Amorphous Oxide Semiconductors

Unveiling Charge Transport and Degradation Mechanisms of Aqueous Zn|α‐MoO₃ Batteries in Conventional Concentration and Water‐in‐Salt Electrolytes: A Multi‐Modal In Situ and Operando Study

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On the thermal decomposition of the zinc(II) hydroxide chlorides Zn5(OH)8Cl2�H2O and ?-Zn(OH)Cl

Cited by 48 publications

References 7 publications

Effect of water vapor on the thermal decomposition process of zinc hydroxide chloride and crystal growth of zinc oxide

Effect of water vapor on the thermal decomposition process of zinc hydroxide chloride and crystal growth of zinc oxide

A General Route to Printable High‐Mobility Transparent Amorphous Oxide Semiconductors

Unveiling Charge Transport and Degradation Mechanisms of Aqueous Zn|α‐MoO3 Batteries in Conventional Concentration and Water‐in‐Salt Electrolytes: A Multi‐Modal In Situ and Operando Study

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Product

Resources

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Unveiling Charge Transport and Degradation Mechanisms of Aqueous Zn|α‐MoO₃ Batteries in Conventional Concentration and Water‐in‐Salt Electrolytes: A Multi‐Modal In Situ and Operando Study