The goal of this paper is to study weakly Einstein critical metrics of the volume functional on a compact manifold M with smooth boundary ∂M . Here, we will give the complete classification for an n-dimensional, n = 3 or 4, weakly Einstein critical metric of the volume functional with nonnegative scalar curvature. Moreover, in the higher dimensional case (n ≥ 5), we will established a similar result for weakly Einstein critical metric under a suitable constraint on the Weyl tensor.2010 Mathematics Subject Classification. Primary 53C25; Secondary 53C20, 53C21, 53C24.