One-pot eco-friendly synthesis and supercapacitor applications: Simultaneously oxidation and intercalation of iodinated graphene oxide

Green Chemistry Approach for One‐Step Synthesis of Iodinated Graphene Material for Supercapacitor Applications

“…For i‐graphene, the projected capacitance‐specific value was 535.4 F g −1 . The capacitance value of 398.4 F g −1 is related to i‐GO [53] . According to the findings, iodination improved the specific capacitance of graphene materials by one fold times compared with i‐GO electrode materiasl (Figure 9d).…”

“…The capacitance value of 398.4 F g À 1 is related to i-GO. [53] According to the findings, iodination improved the specific capacitance of graphene materials by one fold times compared with i-GO electrode materiasl (Figure 9d). However, the specific capacitance is enhanced by more than two-fold due to the significant role played by iodine on the surface of graphene derivatives.The increase in the specific capacitance as a result of the electrochemical charge penetration reaction rate, ion diffusion, and intercalation of iodine content into the graphene layer surface polarization is due to the increased interlayer d-spacing value caused by the addition of larger ions with high iodine moieties, which may make it simpler for a large number of ions to enter the interface between the electrode and electrolyte for energy storage.…”

Green approach for the synthesis of monolayer reduced graphene oxide: one-step protocol with simultaneous iodination and reduction

“…These peak values are similar to those reported in the literature. 22 After reduction without any modification of the iodine reversible process, the intensity ratio of the oxygen band decreased with the enhancement of the d (C-C peak) carbon band. In contrast, the two peak modes were converted (i-GO) to a single peak mode (i-RGO).…”

“…19 Iodine-doped RGO (i-RGO) was utilized as an anode material for sodium-ion batteries reported by Li et al 20 Iodine was used as a catalyst and dopant in the synthesis of an iodine-doped polyaniline-reduced graphene oxide composite hydrogel, according to Wang et al 21 We previously described a simple one-pot procedure for iodine and oxygen intercalation onto a graphite surface using NaIO 4 , an environmentally friendly oxidant, and m-CPBA, a post-oxidizing agent for supercapacitor applications. 22 However, above mentioned methods, are involved at least a two-step synthesis process for iodine functionalization and reduction onto the graphene surface. Herein, we focus on iodine and oxygen intercalation (forming i-GO) and the selective removal of oxygen (forming i-RGO), simultaneously a single-step process on the surface of a graphite sheet by a green chemistry approach (Fig.…”