One‐Pot, One‐Step Strategy for the Preparation of Clickable Melamine Based Microporous Organic Polymer Network

Abstract

Although, current preparation methods for microporous organic polymers (MOP) based on coupling or condensations reactions are simple and flexible, they suffer from the requirement of additional modification steps for introducing properties for specific purposes. In the present work, we have developed a simple and rapid synthetic strategy to prepare MOP possessing reactive sites to incorporate any molecules of interest by ''Click Chemistry''. The clickable MOP with high surface area was readily synthesized through Schiff base chemistry using propargylated anthraquinone and melamine in the catalyst free, one-pot process. The versatility of the click coupling on the acetylene functional MOP was demonstrated on a model reaction using independently prepared fluorescent azido-pyrene.

Orthogonal Synthesis of Block Copolymer via Photoinduced CuAAC and Ketene Chemistries

“…Furthermore, the overall rate of the reaction can be tuned by light intensity, irradiation time, and photoactivator concentration . Photoinduced click reactions have been facilitated in the construction of various macromolecular architectures, such as block and graft copolymers, telechelic, star, and network polymers, surface modification, and bioconjugation under UV or visible light irradiation . Recently, photoinduced ketene chemistry has also been introduced as a facile route for the modification of macromolecular structures with high yields.…”

“…Furthermore, the overall rate of the reaction can be tuned by light intensity, irradiation time, and photo activator concentration. [ 11 ] Photoinduced click reactions have been facilitated in the construction of various macromolecular architectures, [12][13][14][15] such as block [ 16,17 ] and graft [18][19][20] copolymers, telechelic, [ 16,21,22 ] star, [ 23 ] and network polymers, [24][25][26][27][28] surface modifi cation, [29][30][31][32][33][34][35] and bioconjugation [36][37][38] under UV or visible light irradiation. [ 39 ] Recently, photoinduced ketene chemistry has also been introduced as a facile route for the modifi cation of macromolecular A novel route for the synthesis of poly(ethylene glycol)-b -polystyrene copolymer, starting from commercially available poly(ethylene glycol) methyl ether and azido terminated polystyrene prepared by atom transfer radical polymerization and subsequent nucleophilic substitution, is applied with simplicity and high effi ciency.…”

An efficient, heterogeneous, reusable atom transfer radical polymerization catalyst

“…Initially, the template microporous poly(aminal) network (MPP) was synthesized via the reaction of melamine and terephthaldehyde in DMSO at 180 °C , . Immobilization of Cu(I) to MPP was then performed by mixing Cu(I)Br and MPP in DMSO at room temperature to form the heterogeneous ATRP catalyst Cu(I)@MPP (Scheme ) . It should also be noted that disproportionation of Cu(I) in DMSO has been reported in the literature.…”

Novel approach with polyfluorene/polydisulfide copolymer binder for high‐capacity silicon anode in lithium‐ion batteries

“…In the former study we published, a different design concerning the use of a conjugated and flexible polymer was presented for the Li‐ion battery application with high capacity. The designed and synthesized conjugated polymer, poly(fluorene phenylene) containing with lateral substituents, namely poly(ethylene glycol) (PEG) chains, as a potential building block for conjugation was used as a binder for Si‐anode with high performance …”

“…The designed and synthesized conjugated polymer, poly(fluorene phenylene) containing with lateral substituents, namely poly(ethylene glycol) (PEG) chains, as a potential building block for conjugation 19,20 was used as a binder for Si-anode with high performance. [21][22][23][24][25][26] Here, our strategy is to design, synthesis, and testing of the prepared conductive and polymer binder for high capacity silicon anode. For this purpose, we synthesized a polymer binder having fluorene and disulfide functional groups to maintain high electronic conductivity and adhesion.…”