One-pot scalable fabrication of an oligomeric phosphoramide towards high-performance flame retardant polylactic acid with a submicron-grained structure

Xue, Yijiao; Shen, Mingxia; Zheng, Yifei; Tao, Wenzhu; Han, Yanxin; Li, Weidong; Song, Pingan; Wang, Hao

doi:10.1016/j.compositesb.2019.107695

Cited by 131 publications

(57 citation statements)

References 51 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…11), probably attributed to the hydrogen bond interaction. The residual yield of the PES/0.5%PPZn is the lowest at 600 °C, perhaps related to the catalytic effect of the P element of uniform dispersed PPZn on the pyrolysis of PES 65,66 …”

Section: Resultsmentioning

confidence: 98%

Crystallization kinetics, aggregated structure and thermal stability of biodegradable poly(ethylene succinate) manipulated by a biocompatible layered metal phosphonate as an efficient nucleator

Jia

Zhou

Xie³

et al. 2021

Polymer International

View full text Add to dashboard Cite

A P‐ and Zn‐containing organic/inorganic hybrid layered metal phosphonate (PPZn) as a biocompatible nucleator was incorporated into biodegradable poly(ethylene succinate) (PES) polyester to investigate the effect of the PPZn on the crystallization behavior, crystal and aggregated structure, crystal morphology and thermal stability of the PES. Two traditional inorganic nucleators (Talc and BN) were utilized for comparison with the PPZn. The PPZn exhibited markedly higher nucleation effect than the Talc and BN. The PPZn significantly enhanced the Tc and crystallization rate, and shortened the crystallization time of the PES, as confirmed by the crystallization kinetics. Hydrogen bond interaction exists between the PPZn and PES C=O group and between the PPZn and PES amorphous C–O–C group, which facilitates the uniform dispersion of the PPZn in the PES matrix. The nucleation of the PES is mainly attributed to good crystal lattice matching between the PES and PPZn. The PPZn slightly increased the thermal degradation temperature of the PES below 380 °C. © 2021 Society of Chemical Industry

show abstract

Section: Resultsmentioning

confidence: 98%

Crystallization kinetics, aggregated structure and thermal stability of biodegradable poly(ethylene succinate) manipulated by a biocompatible layered metal phosphonate as an efficient nucleator

Jia

Zhou

Xie³

et al. 2021

Polymer International

View full text Add to dashboard Cite

show abstract

“…36 The stretching vibration peak of P O P also appeared at 836 cm À1 , suggesting that phosphorous cross-linked char layer generated. 37,38 The results proved that the char residue of PLA/PU mainly consists of aromatic chars and phosphorus carbon complex mixed with oxygen and nitrogen elements.…”

Section: Characteristics Of Pu/plla Compositesmentioning

confidence: 92%

Antiflaming poly(L‐lactide) by synthesizing polyurethane with phosphorus and nitrogen

Sun

Shen

Wei

et al. 2021

Polymers for Advanced Techs

View full text Add to dashboard Cite

A novel polyurethane containing phosphorus and nitrogen (PU) was synthesized and characterized with 1 H-NMR, FTIR, and GPC. It was served as flame retardant to blend with poly(L-lactide) (PLLA) through solution casting technique. PU particle dispersed in PLLA substrate irregularly and improved the crystallinity of PLLA. The initial decomposition temperature of PLLA composite was significantly lower, but char residue increased. Flame retardancy and mechanical properties of PU/PLLA blends were evaluated. When the blend ratio of PU/PLLA was 10 wt%, LOI was 26.8%, and UL94 test reached V-2 grade. The inflaming retarding mechanism was outlined. The tensile strength of PLLA blend was 42.8 MPa, while its elongation at break was only 2%. By adjusting PU and adding compatilizer, the balance between flame retardancy and good mechanical properties of PLLA would be controlled.

show abstract

“…Further, the flame retardancy of PBS/AlPi composites was investigated by cone calorimeter testing, which is useful to provide various important information about fire risk during combustion (Zanetti et al, 2002;Wang et al, 2020a;Xue et al, 2020b;Xu et al, 2020), such as time to ignition (TTI), heat and smoke release, and mass loss. First, heat release rates (HRR) and combustion time curves for PBS samples are shown in Figure 3A, and detailed parameters are listed in Table 3.…”

Section: Flammability Properties Of Pbs Compositesmentioning

confidence: 99%

Investigating the Effect of Aluminum Diethylphosphinate on Thermal Stability, Flame Retardancy, and Mechanical Properties of Poly(butylene succinate)

et al. 2021

View full text Add to dashboard Cite

Poly(butylene succinate) is one of the most promising biodegradable polymers, but its applications are limited by poor flame retardancy. In this work, poly(butylene succinate)/diethylphosphinate (PBS/AlPi) composites were fabricated to investigate the effect of AlPi on their thermal stability, flame retardancy, and mechanical properties. It was found that the high content of AlPi decreased the thermal stability of PBS, and the decrease became stronger under the air atmosphere. When the content of AlPi reached 25wt%, the flame retardancy was improved with limited oxygen index (LOI) of 29.5%, V0 rating in UL-94 vertical burning test, and 49.3% reduction on the peak of heat release rate (PHRR) in cone calorimeter test. Meanwhile, the addition of AlPi could improve the mechanical properties of PBS with high tensile strength and Young’s modulus, which was ascribed to the compatible effect of maleic anhydride-grafted poly(butylene succinate) (PBS-g-MA) with good filler dispersion and strong matrix-particles interaction. Thus, the AlPi was an effective flame retardant to PBS, so that PBS/AlPi composites displayed excellent flame retardancy without seriously sacrificing other comprehensive performances.

show abstract

One-pot scalable fabrication of an oligomeric phosphoramide towards high-performance flame retardant polylactic acid with a submicron-grained structure

Cited by 131 publications

References 51 publications

Crystallization kinetics, aggregated structure and thermal stability of biodegradable poly(ethylene succinate) manipulated by a biocompatible layered metal phosphonate as an efficient nucleator

Crystallization kinetics, aggregated structure and thermal stability of biodegradable poly(ethylene succinate) manipulated by a biocompatible layered metal phosphonate as an efficient nucleator

Antiflaming poly(L‐lactide) by synthesizing polyurethane with phosphorus and nitrogen

Investigating the Effect of Aluminum Diethylphosphinate on Thermal Stability, Flame Retardancy, and Mechanical Properties of Poly(butylene succinate)

Contact Info

Product

Resources

About