One-pot synthesis of poly(triazole-graft-caprolactone) via ring-opening polymerization combined with click chemistry as a novel strategy for graft copolymers

Güngör, Füsun Şeyma; Kışkan, Barış

doi:10.1016/j.reactfunctpolym.2013.12.005

Cited by 23 publications

(8 citation statements)

References 49 publications

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“…In all cases discussed above, a second modication through an esterication reaction was shown to give doubly-functionalised structures. [84][85][86][87] Finally, this strategy was applied in the preparation of an amphipathic homopolymer library and shown to have siRNA delivery capacity (Fig. 1).…”

Section: Functionalisation With Thiolsmentioning

confidence: 99%

Post-polymerization modification reactions of poly(glycidyl methacrylate)s

2017

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Section: Functionalisation With Thiolsmentioning

confidence: 99%

Post-polymerization modification reactions of poly(glycidyl methacrylate)s

2017

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“…Formation of the hydroxyl group is an important aspect of the thiol‐epoxy reaction. It allows for subjecting the prepared materials to a subsequent functionalization reaction . This goal can be achieved by an esterification reaction employing (activated) acid molecules .…”

Section: Attributes Of the Base‐catalyzed Thiol‐epoxy Reactionmentioning

confidence: 99%

Thiol‐epoxy “click” chemistry: Application in preparation and postpolymerization modification of polymers

Stuparu

Khan

2016

J. Polym. Sci. Part A: Polym. Chem.

136

104

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Base-catalyzed reaction between a thiol and an epoxide group is a simple fusion process that leads to the formation of a b-hydroxythio-ether linkage. This reaction is efficient, regio-selective, and fast. In addition, it produces a reactive hydroxyl group upon completion. Therefore, it is of considerable potential in synthesis of reactive and functional soft materials. Here, we discuss the fundamental aspects of this process, the so-called thiol-epoxy "click" reaction, and its utility in the preparation and post-polymerization functionaliza-tion of polymers and crosslinked networks. Furthermore, its application in surface modification of solid substrates is also considered. Finally, utility of multifunctional materials created using the thiol-epoxy reaction is discussed in the biomedical arena.

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“…[11,22] For post-functionalization of organic materials copper catalyzed 1,3-Huisgen dipolar cycloaddition reaction also referred to as the copper-catalyzed azideÀalkyne click abbreviated CuAAC was studied extensively during the last years. [16,[23][24][25][26][27][28][29][30] Due to their efficiency, modularity, chemoselectivity, orthogonality, and regioselectivity, CuAAC reactions are widely used in many fields ranging from material and polymer sciences to the biomedical and pharmaceutical sciences. [23,[31][32][33] In the related work from the authors' laboratory, linear and hyper-branched polymers and block polymers with thermoactive-, photo-, electro-, and bio-functionalities were successfully prepared through CuAAC reactions.…”

Section: Introductionmentioning

confidence: 99%

“…For post‐functionalization of organic materials copper catalyzed 1,3‐Huisgen dipolar cycloaddition reaction also referred to as the copper‐catalyzed azide−alkyne click abbreviated CuAAC was studied extensively during the last years . Due to their efficiency, modularity, chemoselectivity, orthogonality, and regioselectivity, CuAAC reactions are widely used in many fields ranging from material and polymer sciences to the biomedical and pharmaceutical sciences .…”

Section: Introductionmentioning

confidence: 99%

One‐Pot, One‐Step Strategy for the Preparation of Clickable Melamine Based Microporous Organic Polymer Network

Taşkın

Kışkan

Weber

et al. 2015

Macro Materials & Eng

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Although, current preparation methods for microporous organic polymers (MOP) based on coupling or condensations reactions are simple and flexible, they suffer from the requirement of additional modification steps for introducing properties for specific purposes. In the present work, we have developed a simple and rapid synthetic strategy to prepare MOP possessing reactive sites to incorporate any molecules of interest by ''Click Chemistry''. The clickable MOP with high surface area was readily synthesized through Schiff base chemistry using propargylated anthraquinone and melamine in the catalyst free, one-pot process. The versatility of the click coupling on the acetylene functional MOP was demonstrated on a model reaction using independently prepared fluorescent azido-pyrene.

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One-pot synthesis of poly(triazole-graft-caprolactone) via ring-opening polymerization combined with click chemistry as a novel strategy for graft copolymers

Cited by 23 publications

References 49 publications

Post-polymerization modification reactions of poly(glycidyl methacrylate)s

Post-polymerization modification reactions of poly(glycidyl methacrylate)s

Thiol‐epoxy “click” chemistry: Application in preparation and postpolymerization modification of polymers

One‐Pot, One‐Step Strategy for the Preparation of Clickable Melamine Based Microporous Organic Polymer Network

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