Opportunities and challenges of high-pressure ion exchange chromatography for nuclide separation and enrichment

Xiao, Weixiang; Pan, Duoqiang; Niu, Zhiwei; Yang, Fan; Wu, Sirui; Wu, Wangsuo

doi:10.1016/j.cclet.2022.03.017

Cited by 16 publications

(1 citation statement)

References 144 publications

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“…As a cost-effective method, the ion exchange process normally involves low-cost materials and convenient operations. However, it is very sensitive to the pH of an aqueous solution and can be used only at low concentrated metal solutions [ 6 ]. Chemical precipitation is widely used because of its simple operation [ 7 ].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of Novel Thiosalicylate-based Solid-Supported Ionic Liquid for Removal of Pb(II) Ions from Aqueous Solution

2023

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The main objectives of this study are to synthesize a new solid-supported ionic liquid (SSIL) that has a covalent bond between the solid support, i.e., activated silica gel, with thiosalicylate-based ionic liquid and to evaluate the performance of this new SSIL as an extractant, labelled as Si-TS-SSIL, and to remove Pb(II) ions from an aqueous solution. In this study, 1-methyl-3-(3-trimethoxysilylpropyl) imidazolium thiosalicylate ([MTMSPI][TS]) ionic liquid was synthesized and the formation of [MTMSPI][TS] was confirmed through structural analysis using NMR, FTIR, IC, TGA, and Karl Fischer Titration. The [MTMSPI][TS] ionic liquid was then chemically immobilized on activated silica gel to produce a new thiosalicylate-based solid-supported ionic liquid (Si-TS-SSIL). The formation of these covalent bonds on Si-TS-SSIL was confirmed by solid-state NMR analysis. Meanwhile, BET analysis was performed to study the surface area of the activated silica gel and the prepared Si-TS-SSIL (before and after washing with solvent) with the purpose to show that all physically immobilized [MTMSPI][TS] has been washed off from Si-TS-SSIL, leaving only chemically immobilized [MTMSPI][TS] on Si-TS-SSIL before proceeding with removal study. The removal study of Pb(II) ions from an aqueous solution was carried out using Si-TS-SSIL as an extractant, whereby the amount of Pb(II) ions removed was determined by AAS. In this removal study, the experiments were carried out at a fixed agitation speed (400 rpm) and fixed amount of Si-TS-SSIL (0.25 g), with different contact times ranging from 2 to 250 min at room temperature. The maximum removal capacity was found to be 8.37 mg/g. The kinetics study was well fitted with the pseudo-second order model. Meanwhile, for the isotherm study, the removal process of Pb(II) ions was well described by the Freundlich isotherm model, as this model exhibited a higher correlation coefficient (R2), i.e., 0.99, as compared to the Langmuir isotherm model.

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Section: Introductionmentioning

confidence: 99%