The present research is aimed at investigating processes associated with learning how to drive safely. We were particularly interested in implicit mechanisms related to the automatic processing system involved in decision making in risky situations (Slovic et al., 2007). The operation of this system is directly linked to experiential and emotional reactions and can be monitored by measuring psychophysiological variables, such as skin conductance responses (SCRs). We focused specifically on the generalization of previously acquired skills to new and never before encountered road scenarios. To that end, we compared the SCRs of two groups of participants engaged, respectively, in two distinctive modes of moped-riding training. The active group proceeded actively, via moped, through several simulated courses, whereas the passive group watched video of the courses performed by the former group and identified hazards. Results indicate that the active group not only demonstrated improved performance in the second session, which involved the same simulated courses, but also showed generalization to new scenes in the third session. Moreover, SCRs to risky scenes, although present in both groups, were detectable in a higher proportion in the active group, paralleling the degree of risk confronted as the training progressed. Finally, the anticipatory ability demonstrated previously (and replicated in the present study), which was evident in the repeated performance of a given scenario, did not seem to generalize to the new scenarios confronted in the last session.