“…Arguably, materials with a lower work function that operate at a lower temperature are noted to release more electrons [29] , [30] . Consequently, the work function is of tremendous technological importance in many applications such as thermionic energy converters [31] , [32] , printed and organic electronics [42] , [43] , [44] , emerging perovskite solar cells technology fluorescent light tube [45] , electron emission gadgets (terahertz sources) [46] , [47] , scientific instruments that use electron sources [30] , [39] , [40] , [41] , catalysis [42] , [43] , [50] , [51] , electrochemistry [52] , [53] , [54] , corrosion resistance [25] , [55] , [56] and as an interfacial diagnostic tool in material [57] . These novel applications are realizable if the materials are mechanically, chemically and thermally stable (thoriated tungsten and lanthanum hexaboride), preferably caesiated metals of low work function [48] , [49] , [58] , [59] , as applied in thermionic energy converter [38] , [60] , [61] , [62] , [63] .…”