Optical and photoelectrical properties of ReS2 single crystals

Friemelt, K.; Kulikova, L. F.; Kulyuk, L.; Siminel, Anatolii V.; Arushanov, E.; Kloc, Ch.; Bücher, E.

doi:10.1063/1.362602

Cited by 36 publications

(31 citation statements)

References 15 publications

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“…Along Re chain in this material [15,16]. Angle-dependent Raman scattering measurements of these samples show strong anisotropy in the 214 cm −1 peak intensity with clear twofold symmetry, as seen in recent reports [9,17,18].…”

Section: Methodsmentioning

confidence: 59%

Narrow-band anisotropic electronic structure of ReS2

et al. 2017

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We have used angle-resolved photoemission spectroscopy to investigate the band structure of ReS 2 , a transitionmetal dichalcogenide semiconductor with a distorted 1T crystal structure. We find a large number of narrow valence bands, which we attribute to the combined influence of structural distortion and spin-orbit coupling. We further show how this leads to a strong in-plane anisotropy of the electronic structure, with quasi-one-dimensional bands reflecting predominant hopping along zigzag Re chains. We find that this does not persist up to the top of the valence band, where a more three-dimensional character is recovered with the fundamental band gap located away from the Brillouin zone center along k z . These experiments are in good agreement with our density-functional theory calculations, shedding light on the bulk electronic structure of ReS 2 , and how it can be expected to evolve when thinned to a single layer.

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Section: Methodsmentioning

confidence: 59%

Narrow-band anisotropic electronic structure of ReS2

et al. 2017

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“…[10] Moreover, the distorted T phase is supposed to induce anisotropic electronic, optical and mechanical properties in ReS 2 . [1,8,11,12] Due to the direct bandgap and anisotropic crystal structure of ReS 2 , it therefore is expected to have a wide the growth respectively (for more details see the Experimental Section; Figure S1 in the Supporting Information). The preference of formation of large-area ReS 2 film on sapphire substrate might be attributed to the weak van der Waals interaction between them.…”

Section: Introductionmentioning

confidence: 99%

Large‐Area Bilayer ReS₂ Film/Multilayer ReS₂ Flakes Synthesized by Chemical Vapor Deposition for High Performance Photodetectors

Hafeez

Gan

et al. 2016

Adv Funct Materials

213

177

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Rhenium disulfide (ReS 2 ) is attracting more and more attention for its thickness-depended direct band gap. As a new appearing 2D transition metal dichalcogenide, the studies on synthesis method via chemical vapor deposition (CVD) is still rare. Here a systematically study on the CVD growth of continuous bilayer ReS 2 film and single crystalline hexagonal ReS 2 flake, as well as their corresponding optoelectronic properties is reported. Moreover, the growth mechanism has been proposed, accompanied with simulation study. High-performance photodetector based on ReS 2 flake shows a high responsivity of 604 A·W −1 , high external quantum efficiency of 1.50 × 10 5 %, and fast response time of 2 ms. ReS 2 film-based photodetector exhibits weaker performance than the flake one; however, it still demonstrates a much faster response time (≈10 3 ms) than other reported CVD-grown ReS 2 -based photodetector (≈10 4 -10 5 ms). Such good properties of ReS 2 render it a promising future in 2D optoelectronics.

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“…The triclinic crystal structure of ReS2 leads to polarization dependent optical absorption. [65] The anisotropic absorption coefficient and transient absorption was maximum when the light polarization was parallel to the Re chains, and minimum when perpendicularly polarized. [72] Many-body perturbation theory computations have shown that the lowest-energy bright excitons of distorted 1T ReS2 exhibit a perfect figure-eight shape polarization -which is unusual for hexagonal TMDs.…”

Section: Excitonic and Absorption Propertiesmentioning

confidence: 99%

“…Both the monolayer and bulk ReS2 is a direct gap semiconductor with a bandgap of ~1.55 eV for monolayer and 1.47 for bulk, respectively. [35,65] In ReS2 (i) overlapping of electron wavefunctions from adjacent layers is so weak that a modulation of the interlayer distance cannot renormalize the band structure, implying that…”

Section: Band Structure and Electronic Transportmentioning

confidence: 99%

Advent of 2D Rhenium Disulfide (ReS₂): Fundamentals to Applications

Rahman

Davey

Qiao

2017

Adv Funct Materials

336

279

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Rhenium disulfide (ReS2) is a two dimensional (2D) group VII transition metal dichalcogenide (TMD). It is attributed with structural and vibrational anisotropy, layer independent electrical and optical properties, and metal-free magnetism properties. These properties are unusual compared with more widely used group VI-TMDs e.g. MoS2, MoSe2, WS2 and WSe2. Consequently, it has attracted significant interest in recent years and is now being used for a variety of applications including solid state electronics, catalysis, and, energy harvesting and energy storage. It is anticipated that ReS2 has the potential to be equally used in parallel with isotropic TMDs from group VI for all known applications and beyond.Therefore, a review on ReS2 is very timely. In this first review on ReS2, we critically analyze the available synthesis procedures and their pros-cons, atomic structure and lattice symmetry, crystal structure and growth mechanisms with an insight to the orientation and architecture of domain and grain boundaries, decoupling of structural and vibrational properties, anisotropic electrical, optical and magnetic properties impacted by crystal imperfections, doping and adatoms adsorptions, and the contemporary applications in different areas.

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Optical and photoelectrical properties of ReS2 single crystals

Cited by 36 publications

References 15 publications

Narrow-band anisotropic electronic structure of ReS2

Narrow-band anisotropic electronic structure of ReS2

Large‐Area Bilayer ReS₂ Film/Multilayer ReS₂ Flakes Synthesized by Chemical Vapor Deposition for High Performance Photodetectors

Advent of 2D Rhenium Disulfide (ReS₂): Fundamentals to Applications

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Optical and photoelectrical properties of ReS2 single crystals

Cited by 36 publications

References 15 publications

Narrow-band anisotropic electronic structure of ReS2

Narrow-band anisotropic electronic structure of ReS2

Large‐Area Bilayer ReS2 Film/Multilayer ReS2 Flakes Synthesized by Chemical Vapor Deposition for High Performance Photodetectors

Advent of 2D Rhenium Disulfide (ReS2): Fundamentals to Applications

Contact Info

Product

Resources

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Large‐Area Bilayer ReS₂ Film/Multilayer ReS₂ Flakes Synthesized by Chemical Vapor Deposition for High Performance Photodetectors

Advent of 2D Rhenium Disulfide (ReS₂): Fundamentals to Applications