The sol-gel process is a friendly room temperature method to prepare transparent glasses in the form of monoliths, films, and fibers. The zinc oxide films have been obtained by sol-gel method, which are very important materials in the ceramic technology due to their piezoelectric properties and applications in various pressure transducers and acoustic-optic devices, surface and bulk acoustic wave devices, and solar cells. Structure and characteristic ultraviolet-blue emissions of amorphous and crystalline zinc oxide thin films-coated glass substrates by dip-coating deposition are explained by photoluminescence studies in this chapter.