The detonation of a metalized explosive generates a fireball that has a spatially non-uniform distribution of particle concentration and gas temperature. The transient gas temperature field must be probed with ruggedized spatially-and temporally-resolved diagnostics. The use of in-situ thermocouples for temperature measurements within multiphase fireballs is demonstrated. Although the thermocouple temperature lags behind the local gas temperature, the transient gas temperature is assessed by modeling the sensor assuming first-order response and using two analysis methods: (1) when the thermocouple temperature trace reaches a local extrema, the thermocouple temperature is instantaneously equal to the local gas temperature, and (2) reconstructing the gas temperature trace using multiple co-located thermocouples of different lag responses. The temperature history within the fireball at various distances is presented for charges consisting of packed beds of particles saturated with liquid nitromethane. The results for reactive particles (Al, Ti, Zr) are compared with non-reactive particles (Fe), as well as homogeneous NM charges. For NM charges, a maximum gas temperature of about 1100 K occurs at times on the order of 100's of milliseconds, less than the temperature of the burning soot in the fireball (~1900 K). With Al particles, the gas temperature is spatially non-uniform due to particle jetting and non-uniform particle combustion, but gas temperatures up to about 1800 K are recorded for times up to 0.5 s, less than the temperature of the burning particles (2 700 K). Inert particles act as a heat sink and the thermocouple temperatures recorded did not exceed 400 K.