Multi-view videos (MVVs) provide immersive viewing experience, at the cost of traffic load increase for wireless networks. In this paper, we would like to optimize MVV transmission in a multiuser wireless network by exploiting both natural multicast opportunities and view synthesis-enabled multicast opportunities. Specifically, we first establish a mathematical model to specify view synthesis at the server and each user, and characterize its impact on multicast opportunities. This model is highly nontrivial and fundamentally enables the optimization of view synthesis-based multicast opportunities. For given video quality requirements of all users, we consider the optimization of view selection, transmission time and power allocation to minimize the average weighted sum energy consumption for view transmission and synthesis. In addition, under the energy consumption constraints at the server and each user respectively, we consider the optimization of view selection, transmission time and power allocation and video quality selection to maximize the total utility. These two optimization problems are challenging mixed discrete-continuous optimization problems. For the first problem, we propose an algorithm to obtain an optimal solution with reduced computational complexity by exploiting optimality properties. For each problem, to reduce computational complexity, we also propose a low-complexity algorithm to obtain a suboptimal solution, using Difference of Convex (DC) programming. Finally, numerical results show the advantage of the proposed solutions over existing ones, and demonstrate the importance of the optimization of view synthesis-enabled multicast opportunities in MVV transmission.Index Terms-Multi-view video, view synthesis, multicast, convex optimization, DC programming.