Criteria defining higher-order sub-Poissonian-like fields are given using five different quantities: moments of I) integrated intensity, II) photon number, III) integrated-intensity fluctuation, IV) photon-number fluctuation, and V) elements of photocount and photon-number distributions. Relations among the moment criteria are revealed. Performance of the criteria is experimentally investigated using a set of potentially sub-Poissonian fields obtained by post-selection from a twin beam. The criteria based on moments of integrated intensity and photon number and those using the elements of photocount distribution are found as the most powerful. States nonclassical up to the fifth order are experimentally reached in the former case, even the ninth-order non-classicality is observed in the latter case.Nonclassical properties of optical fields and their characterization have been in the center of attention from the beginning of quantum optics. The simplest, and from the experimental point of view the most natural, way how to achieve this is based on the determination of second-order moments of fluctuations of the measured quantities, that violate certain inequalities for nonclassical fields. This approach resulted in the introduction of principal squeeze variance of electric-field amplitudes and the Fano factor to quantify nonclassical phase fluctuations and photonnumber fluctuations, respectively [1,2]. The Fano factor represents the most important quantity for optical fields characterized by standard quadratic detectors, for which it identifies sub-Poissonian fields. It has been used to quantify nonclassical light originating in resonance fluorescence [3,4], Franck-Hertz experiment [5], high-efficiency light-emitting diodes [6], second-harmonic generation [7,8], parametric deamplification [9], secondsubharmonic generation [10], feed-forward action on the beam [11,12] or light generated in micro-cavities by passing atoms [13]. Highly sub-Poissonian fields have also been reached by post-selection from cw [14][15][16] and pulsed twin beams (TWB) [17][18][19][20][21].The Fano factor F defined in terms of photon-number moments as F = (∆n) 2 / n identifies sub-Poissonian fields if F < 1; ∆n ≡n − n denotes the fluctuation of photon-number operatorn given in terms of the annihilation (â) and creation (â † ) operators asn ≡â †â . Symbol stands for the mean value. This condition when expressed in the moments of integrated intensity W (or equivalently in the normally-ordered moments of photon number, i.e. W k ≡ â †kâk [22][23][24]), (∆W ) 2 = â †2â2 − â †â 2 < 0 [for the relation between the moments that is used for determining intensity moments from the experimental data, see * jan.perina.jr@upol.cz Eq. (3) below], reveals the relation with the general definition of non-classicality: A field is nonclassical provided that its (normally-ordered) Glauber-Sudarshan quasidistribution P (as a function of complex field amplitudes) attains negative values or even does not exist as a regular function [25,26]. The consideration of th...