Optimization of Pretreatment and Alkaline Cooking of Wheat Straw on its Pulpability Using Response Surface Methodology

Abstract

The dissolution rates of the chemical compositions of alcohol-benzene extractables (ABE), holocellulose, hemicellulose, and lignin in wheat straw (WS) under different pretreatment conditions were investigated. The individual and interactive effects of three independent parameters, namely, sodium hydroxide (NaOH) dosage (x1: 8 wt.% to 12 wt.%), sodium sulfide (Na2S) dosage (x2: 10 wt.% to 18 wt.%), and time to maximum temperature (x3: 100 min to 140 min) on screened yield, Kappa number, and brightness of wheat straw pulp (WSP) were analyzed via response surface methodology (RSM). The results suggested that the quadratic equations were in good agreement with the experimental figures in the present work. The relative errors of verification results were less than 5%, which indicated that the selected model for explaining the relationship between the variables and the responses was correct. In addition, the relationships between the screened yield, reject yield, brightness, and Kappa number were described and explained. Wheat straw pulpability was optimized in this study via RSM.

Lignin, a biomass crosslinker, in a shape memory polycaprolactone network

“…Following the rapid crosslinking event, the lignin‐based nanocontainer shell surrounds a liquid aqueous core, which can be used to efficiently release the encapsulated hydrophilic substances such as drugs, fertilizers, and pesticides. Similar methods are used to synthesize polyurethane out of lignin . Scarica et al pretreated lignin with succinic anhydride and cured the succinylated lignin by self‐polyesterification with external crosslinkers, sodium hypophosphite, and hexamethoxy–methylmelamine‐based crosslinking agent .…”