An experiment to search for the alpha decay of 112 Cs has been performed at the Holifield Radioactive Ion Beam Facility (HRIBF) at Oak Ridge National Laboratory. The alpha decay of 112 Cs was not observed, thus setting the upper limit of the alpha branching ratio at 0.26%. The half-life of 112 Cs was measured as 506 ± 55 µs. In the same measurement the decay properties of its proton decay daughter 111 Xe were also reinvestigated. The newly measured alpha branching ratio for 111 Xe is 10.4 ± 1.9 %. The experimental proton separation energies Sp for odd-Z nuclei above 100 Sn were compared to shell model calculations. The calculated proton separation energies for 103 Sb and 102 Sb point to half-lives of the order of 10 ps and 1 ns, respectively.