“…8 -12͒ causes charge accumulation. In this ordering, monolayers of GaP-rich and InP-rich atomic planes alternatively appear along ͓1 11͔ or ͓11 1͔, which can be expressed by using order parameter as Ga 0.5ϩ/2 In 0.5Ϫ/2 P/Ga 0.5Ϫ/2 In 0.5ϩ/2 P. 8,10,11 Therefore, macroscopic polarization, which is originated from the piezoelectric effect [13][14][15] and microscopic spontaneous polarization, 5 is induced in the ordered Ga 0.5 In 0.5 P. In a GaAs/Ga 0.5 In 0.5 P/GaAs double heterostructure, 2,4,5 this macroscopic polarization causes negative and positive sheet charges at both the edges of Ga 0.5 In 0.5 P layer of the GaAs/Ga 0.5 In 0.5 P and Ga 0.5 In 0.5 P/GaAs interfaces, respectively. In the Ga 0.5 In 0.5 P/GaAs single heterostructure, it has been reported that electron accumulation occurs in the GaAs side.…”