Organic/inorganic electrodes (ORINELs) with continuous phase components

Synthesis and characterization of poly(2,5-dimethoxyaniline) and poly(aniline-Co-2,5-dimethoxyaniline): The processable conducting polymers

“…Polyaniline, however, is severely limited in view of its insolubility in common organic solvents making its characterization rather intricate. Recently, synthesis of some substituted polyanilines which are soluble in organic solvents as well as in water beside being thermally and environmentally stable have been achieved (Watanabe et al 1987;Aurian-Blajeni et al 1988;Somasiri and MacDiarmid 1988). In order to obtain materials with superior electrical and optical properties we have selected dimethoxy aniline derivative in this investigation, which is polymerized to get more regular and processable conducting polymer.…”

A Study of Tungsten Trioxide and Polyaniline Composite Films: I . Electrochemical and Electrochromic Behavior

“…This will eliminate the highly reactive lithium metal as the negative electrode., simplify the integration process, and permit the use of packaging materials that would not have been suitable for deposition on the reactive and soft Li metal. The rocking-chair-type cells have been demonstrated in the bulk tbrm for LiCoOJC (5,6), LiNiOjC (petroleum coke) (7), and LiMn204/C (petroleum coke) (8) systems, where the two electrodes are immersed in liquid electrolyte. High open-circuit voltage (OCV) and high energy densities require a positive electrode that can intercalate lithium ion at a high voltage.…”

“…The presence of polymer substances around the WO.~ film restricts the diffhsion of W ~ ~ to the bulk electrolyte, thus enabling most of the dissolved tungsten to be replated at cathodic potentials. In recent years, there have been several reports on the preparation of composite films based on the electrochemical polymerization of pyrrole or aniline in the presence of WO~, V20~, tetrathiomolybdate anions or anodi-caUy formed IrO., films (4)(5)(6)(7). These studies are mainly concentrated on their photoelectrochemical properties.…”