Organotin Compounds

Structures of the Pentaphenylcyclopentadienyl Radical, (Pentaphenylcyclopentadienyl)tin(IV) Trichloride, and Bromo(chloro)bis(tetrahydrofuran)tin(II): Products of the Reaction of C5Ph5X with SnX2 (X = Cl, Br)

“…The Sn−C1−Cp(ring centroid) angle is 99.5°, and the deviation of the C11−C1 vector from the cyclopentadienyl plane is 32.6°, both values being close to the respective parameters in C 5 Me 5 SnI 3 (99.8° and 28.8°, respectively) . The Sn−C1 distance is somewhat longer than normal tin(IV)−carbon bond lengths (2.10−2.18 Å), but again similar to the value in C 5 Me 5 SnI 3 (2.25 Å) 1 ORTEP drawing (50% probability) of C 5 Ph 5 SnCl 3 ( 1 ); the hydrogen atoms have been omitted for clarity.…”

Synthesis of New Tin(iv) Compounds of Substituted Diphenylsulfide Derivatives and Their Complexes With Some Neutral Ligands

“…The chemistry of Sn(SR) 4 , R x Sn(SR 0 ) 4-x , tin(II) thiolate and of the corresponding lead compounds have been reviewed [1][2][3][4] . Substituted disulfide derivatives of main group metals have received much less attention than those of the corresponding transition metals.…”

“…The chemistry of Sn(SR) 4 , R x Sn(SR 0 ) 4-x , tin(II) thiolate and of the corresponding lead compounds have been reviewed [1][2][3][4] . In our recent article, we have describe the direct reaction between bismuth metal with (o-H 2 NC 6 H 4 S) 2 and ( p-MeC 6 H 4 S) 2 in refluxing toluene to give the corresponding bismuth compounds Bi(SC 6 H 4 NH 2 -o) 3 and Bi(SC 6 H 4 Me-p) 3 , respectively 8 . The synthesis of dihalobis(2-pyridinethiolato)tin(IV) by an oxidative-addition reaction of di-2-pyridyldisulfide to tin(II) halides represents an example of preparing other similar dihalodithiolatotin(IV) compounds 7 .…”