Orientation in dehydrohalogenation of 2-iodobutane promoted by ramified tertiary aldoxide bases in dimethyl sulfoxide

Bartsch, Richard A.; Ingram, David D.

doi:10.1021/jo00909a028

Search citation statements

Order By: Relevance

Paper Sections

Select...

Models For Effects Of Base Association Upon Orientation1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1976

2001

Publication Types

Select...

Article4

Other1

Book1

Relationship

Self Cite1

Independent5

Authors

Journals

Cited by 7 publications

(1 citation statement)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Since ramified free bases possess the advantage of considerably higher reactivity than associated base species, it was of interest to compare the In order to examine this question, orientation in reactions of 2-butyl iodide with a number of tertiary alkoxides in Me2SO was determined. 63 Results are recorded in Table X. None of the sterically congested free bases eclipse the orientation control provided by f-BuOK-f-BuOH (last entry in Table X).…”

Section: Models For Effects Of Base Association Upon Orientationmentioning

confidence: 99%