2007
DOI: 10.1016/j.jinorgbio.2006.09.027
|View full text |Cite
|
Sign up to set email alerts
|

Oxidation of methionines by oxochromium(V) cations: A kinetic and spectral study

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1
1

Citation Types

0
12
0

Year Published

2008
2008
2023
2023

Publication Types

Select...
5
1

Relationship

3
3

Authors

Journals

citations
Cited by 23 publications
(12 citation statements)
references
References 66 publications
(96 reference statements)
0
12
0
Order By: Relevance
“…We have observed large catalytic effects of ligand oxides on the sulfoxidation of organic sulfides with [oxo(salen)chromium(V)] ? ions [36][37][38]. This catalytic effect has been attributed to the strong binding of ligand oxides to the metal center, thereby weakening the M=O bond and facilitating oxygen atom transfer to the substrate.…”
Section: Discussionmentioning
confidence: 99%
See 2 more Smart Citations
“…We have observed large catalytic effects of ligand oxides on the sulfoxidation of organic sulfides with [oxo(salen)chromium(V)] ? ions [36][37][38]. This catalytic effect has been attributed to the strong binding of ligand oxides to the metal center, thereby weakening the M=O bond and facilitating oxygen atom transfer to the substrate.…”
Section: Discussionmentioning
confidence: 99%
“…The catalytic activity of metal-salen ions in oxidation reactions can be tuned not only by making substitutions in the salen ligand, but also by adding donor ligands to the reaction mixture [36][37][38][55][56][57]. The added ligands bind to the axial position of the metal-salen complex and mimic the effects of the axial histidine and thiolate residues found in peroxidases and cytochrome P-450s, respectively [58].…”
Section: Effect Of Axial Ligands On the Oxidation Of Anilinesmentioning
confidence: 99%
See 1 more Smart Citation
“…Also, sulfides are the starting materials for the preparations of other sulfur compounds, such as sulfonium compounds, sulfones and sulfoxides . The study of oxidation of organic sulfides to sulfoxides is of wide interest because of their antioxidant nature and the important role of sulfur compounds in biological systems and intermediates for pharmaceuticals, polymer materials and ligands in asymmetric catalysis . Tetrazoles are some of the most stable nitrogen‐rich heterocyclic compounds that have received considerable attention because tetrazole‐containing molecules have several applications in the field of coordination chemistry, organic synthesis, material science and medicinal chemistry including antiprotozoal, antihypertensive and antibiotic effects …”
Section: Introductionmentioning
confidence: 99%
“…The study of oxidation of organic sulfides is of wide interest because of the important role of sulfur compounds and in particular, sulfur centered radicals in biological systems [34]. As sulfoxidation reactions play vital role in biological systems because of their antioxidant nature [6,[35][36][37][38][39], it is desirable to study the catalytic role of cobalt(II)-salen complexes for the oxidation of sulfides. As far as the nature of the active oxidant species generated from the catalyst cobalt(II)-salen complex and H 2 O 2 is concerned much effort has been attempted in recent years [32,40].…”
Section: Introductionmentioning
confidence: 99%