2016
DOI: 10.1002/ange.201600507
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Oxidationsreaktionen mit bioinspirierten einkernigen Nicht‐Häm‐Oxidometallkomplexen

Abstract: Die selektive Funktionalisierung starker C‐H‐Bindungen sowie die Oxidation von Wasser durch preiswerte und ungiftige Metalle sind einige der Schlüsselziele der heutigen chemischen Forschung. Es wurde vorgeschlagen, dass hochvalente Eisen‐, Mangan‐ und Kupferkerne als reaktive Intermediate an diesen wichtigen Oxidationsreaktionen, die von biologischen Systemen ausgeführt werden, beteiligt sind, was sie zu begehrten Zielobjekten für biomimetische Synthesestudien macht. Die Herstellung und Charakterisierung von M… Show more

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Cited by 48 publications
(1 citation statement)
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“…However, water had not been coordinated until recently to the iron tmc complex. While other axial groups L have been introduced earlier (such as for example, RS − ),, this was much more difficult for water owing to the decomposition reactions described above (however, these only occur if the synthetic procedure is performed incorrectly). Finally, together with the recent report by Que, Cramer, and co‐workers we could demonstrate that an exchange of an oxygen atom between water and [(tmc)Fe=O](OTf) 2 follows at least in part the oxido–hydroxido tautomerism analogous to heme systems.…”
Section: Figurementioning
confidence: 99%
“…However, water had not been coordinated until recently to the iron tmc complex. While other axial groups L have been introduced earlier (such as for example, RS − ),, this was much more difficult for water owing to the decomposition reactions described above (however, these only occur if the synthetic procedure is performed incorrectly). Finally, together with the recent report by Que, Cramer, and co‐workers we could demonstrate that an exchange of an oxygen atom between water and [(tmc)Fe=O](OTf) 2 follows at least in part the oxido–hydroxido tautomerism analogous to heme systems.…”
Section: Figurementioning
confidence: 99%