Oxidative adsorption of methyl mercaptan on nitrogen-enriched bituminous coal-based activated carbon

Microcalorimetric Study of the Catalytic Properties of SBA-15 Modified with Cu or Fe for Adsorption/oxidation of Methyl mercaptane

“…5. The greatest amount adsorbed was found for the Fe/SBA-15 catalyst, even though the breakthrough test had to be stopped at 35 ppm due to the fact that the strongly catalytic nature of this catalyst facilitates rapid oxidation of MM to dimethyl disulfide (DMDS), which is not detected by the sensor used in our experiments; this had already been reported by other authors 11,[14][15][16][17][18] . The capacity of the Cu/SBA-15 catalyst was less.…”

“…To evaluate the capacity of the synthesized samples, catalytic experiments were carried out in the adsorption/oxidation dynamic phase similar to those reported in the literature 3,5,7,11,[13][14][15][16][17][18] in order to make comparisons with our results. The design was adjusted to our laboratory conditions.…”

“…As can be seen from the above listed reactions, the role of iron is to promote formation of thiolate radicals and reduction of oxygen, resulting in the presence of very active superoxide species that go on to form radicals under either wet or dry conditions in the MM removal process [14][15][16][17][18] .…”

“…On the other hand, it was reported that oxidation of methyl mercapthan to dimethyl disulfide takes place at the surface of activated carbons having functional groups such as carboxyl group in dry/wet air [12][13][14] . In addition, there are a few reports on the adsorption/oxidation of methyl mercapthan on surface-modified activated carbons [15][16][17] . Among current problems the most studied is natural gas, a vital component of the world's supply of energy.…”

Development of Activated Carbon Using One Step Carbonization and Activation Reaction by Polymer Blend Method

“…These unique characteristic properties make activated carbon materials very versatile adsorbent material for adsorption of both gaseous and liquid phase molecules. Therefore, activated carbons are useful adsorbents for removing pollutants of different sizes both in liquid and gaseous phase [1][2][3][4][5][6].Advantages of activated carbon materials as adsorbents are that the treated effluent is of high quality, design of the process is simple and operation of process developed or adopted is easy.…”