2020
DOI: 10.1021/acs.iecr.0c05244
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Oxidative Coupling of Light Alkanes to Liquid Fuels Using Isobutane as an Oxygen Carrier and the Alkane Structure–Reactivity Relationship

Abstract: A process scheme for the liquid-phase oxidative coupling of light alkanes (C 3 −C 7 ) to transportation fuels using isobutane as the oxygen carrier is devised. The process consists of (1) liquid-phase oxidation of isobutane to tert-butyl hydroperoxide (TBHP), with tert-butyl alcohol (TBA) coproduct; (2) converting TBHP and TBA over an acid catalyst to di-tert-butyl peroxide (DTBP); (3) using DTBP to generate alkyl radicals from the feed alkane, which are coupled to form heavier alkanes, with TBA as coproduct; … Show more

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