Oxidative rearrangement of alkanal cyanohydrins initiated by peroxydisulfate ions

Ogibin, Yu. N.; Makhova, I. V.; Gorozhankin, S. K.; Nikishin, G. I.

doi:10.1007/bf00954090

Cited by 3 publications

(1 citation statement)

References 6 publications

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“…In 1984, Nikishin and co‐workers described an oxidative rearrangement of alkanal cyanohydrins into mixtures of cyanoalkanoic acids and simple alkanoic acids . The yields were generally modest and mixtures of the two products were formed across the five substrates tested (Scheme ).…”

Section: Conversion Of Sp3 C–h To C–c Bonds With Peroxydisulfatementioning

confidence: 99%

Peroxydisulfate as an Oxidant in the Site‐Selective Functionalization of sp³ C–H Bonds

Sathyamoorthi

Banerjee

2017

ChemistrySelect

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The development of methodology for the site-selective functionalization of sp 3 C-H bonds has irrevocably altered the state of organic synthesis. These methods often rely on the use of strong oxidants in conjunction with transition-metal catalysis. Peroxydisulfate (S 2 O 8 2-) salts are some of the strongest inorganic oxidants known. They are low-cost crystalline solids that are stable at room temperature. Harmless sulfate salts are produced as a byproduct of their reactions, allowing S 2 O 8 2to serve as a 'green' alternative to other commonly employed oxidants. Despite these attractive properties, it has only been in the last ten years that the majority of sp 3 C-H functionalization reactions utilizing S 2 O 8 2for the diversification of complex molecules have been reported. The objective of this review is to provide a useful reference regarding the recent advancement of sp 3 C-H functionalization using S 2 O 8 2and to inspire the invention of new protocols utilizing this remarkable oxidant.

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Section: Conversion Of Sp3 C–h To C–c Bonds With Peroxydisulfatementioning

confidence: 99%

Peroxydisulfate as an Oxidant in the Site‐Selective Functionalization of sp³ C–H Bonds

Sathyamoorthi

Banerjee

2017

ChemistrySelect

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Ammonium Peroxydisulfate

Behrman

2001

Encyclopedia of Reagents for Organic Synthesis

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Ammonium Peroxydisulfate

Behrman¹,

Neufeldt²

2012

Encyclopedia of Reagents for Organic Synthesis

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Oxidative rearrangement of alkanal cyanohydrins initiated by peroxydisulfate ions

Cited by 3 publications

References 6 publications

Peroxydisulfate as an Oxidant in the Site‐Selective Functionalization of sp³ C–H Bonds

Peroxydisulfate as an Oxidant in the Site‐Selective Functionalization of sp³ C–H Bonds

Ammonium Peroxydisulfate

Ammonium Peroxydisulfate

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Oxidative rearrangement of alkanal cyanohydrins initiated by peroxydisulfate ions

Cited by 3 publications

References 6 publications

Peroxydisulfate as an Oxidant in the Site‐Selective Functionalization of sp3 C–H Bonds

Peroxydisulfate as an Oxidant in the Site‐Selective Functionalization of sp3 C–H Bonds

Ammonium Peroxydisulfate

Ammonium Peroxydisulfate

Contact Info

Product

Resources

About

Peroxydisulfate as an Oxidant in the Site‐Selective Functionalization of sp³ C–H Bonds

Peroxydisulfate as an Oxidant in the Site‐Selective Functionalization of sp³ C–H Bonds