Oxygen electroreduction on anthraquinone-modified nickel electrodes in alkaline solution

Kullapere, Marko; Tammeveski, Kaido

doi:10.1016/j.elecom.2007.01.020

Cited by 34 publications

(28 citation statements)

References 49 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[16] In addition, coupling of the anthraquinone redox group through different spacers allows the modification efficiency and yield of each attachment step to be monitored electrochemically. Anthraquinone has previously been directly attached on carbon [13,17,18] or nickel electrodes [19] by electrochemical reduction of the corresponding diazonium salt or electrochemical oxidation of the corresponding carboxylate [20] but, to our knowledge, there are no examples in the literature of grafting of anthraquinone onto a carbon surface by solidphase coupling reactions.…”

Section: Resultsmentioning

confidence: 99%

Covalent Tethering of Organic Functionality to the Surface of Glassy Carbon Electrodes by Using Electrochemical and Solid‐Phase Synthesis Methodologies

Chrétien

Ghanem

Bartlett

et al. 2008

Chemistry A European J

View full text Add to dashboard Cite

Organic linkers such as (N-Boc-aminomethyl)phenyl (BocNHCH2C6H4) and N-Boc-ethylenediamine (Boc-EDA) have been covalently tethered onto a glassy carbon surface by employing electrochemical reduction of BocNHCH2C6H4 diazonium salt or oxidation of Boc-EDA. After removal of the Boc group, anthraquinone as a redox model was attached to the linker by a solid-phase coupling reaction. Grafting of anthraquinone to electrodes bearing a second spacer such as 4-(N-Boc-aminomethyl)benzoic acid or N-Boc-beta-alanine was also performed by following this methodology. The surface coverage, stability and electron transfer to/from the tethered anthraquinone redox group through the linkers were investigated by cyclic voltammetry. The effects of pH and scan rate were studied, and the electron-transfer coefficient and rate constant were determined by using Laviron's equation for the different types of linker. The combination of electrochemical attachment of protected linkers and subsequent modifications under the conditions of solid-phase synthesis provides a very versatile methodology for tailoring a wide range of organic functional arrangements on a glassy carbon surface.

show abstract

Section: Resultsmentioning

confidence: 99%

Covalent Tethering of Organic Functionality to the Surface of Glassy Carbon Electrodes by Using Electrochemical and Solid‐Phase Synthesis Methodologies

Chrétien

Ghanem

Bartlett

et al. 2008

Chemistry A European J

View full text Add to dashboard Cite

show abstract

“…According to literature, anthraquinone grafted nickel electrode exhibits some catalytic activity towards ORR in alkaline medium [46]. This modification was decided to be carried out on carbon-supported nickel oxide nanoparticles NiO x /C, obtained as described in Section 3.1.…”

Section: Chemical Modification Of Nickel Surface By Anthraquinonementioning

confidence: 99%

Ni and/or Co nanoparticles as catalysts for oxygen reduction reaction (ORR) at room temperature

Goubert-Renaudin

Wiȩckowski

2011

Journal of Electroanalytical Chemistry

View full text Add to dashboard Cite

“…The quinonemodified carbon electrodes showed good electrocatalytic properties for a two-electron reduction of O 2 to hydrogen peroxide [11 -22]. Besides carbon electrodes, also metal surfaces (Au [24], Ni [25], Cu [26]) could be modified with quinones by diazonium reduction. There has been a long-standing interest in studying the blocking properties of covalently attached aryl layers [6,7].…”

Section: Introductionmentioning

confidence: 99%

Blocking Behavior of Covalently Attached Anthraquinone Towards Solution‐Based Redox Probes

2010

Self Cite

View full text Add to dashboard Cite

The electrochemical properties of glassy carbon (GC) electrodes modified with 9,10-anthraquinone (AQ) have been investigated. Electrografting of GC surface was carried out from the solution of the AQ diazonium derivative. The blocking action of GC/AQ electrodes for Fe(CN) 3À 6 and Ru(NH 3 ) 3þ 6 redox probes was studied using cyclic voltammetry (CV) and the rotating disk electrode (RDE) method. It was established that the extent of blocking was a function of AQ surface concentration. A peculiar behavior was observed at the potentials of AQ reduction.

show abstract

Oxygen electroreduction on anthraquinone-modified nickel electrodes in alkaline solution

Cited by 34 publications

References 49 publications

Covalent Tethering of Organic Functionality to the Surface of Glassy Carbon Electrodes by Using Electrochemical and Solid‐Phase Synthesis Methodologies

Covalent Tethering of Organic Functionality to the Surface of Glassy Carbon Electrodes by Using Electrochemical and Solid‐Phase Synthesis Methodologies

Ni and/or Co nanoparticles as catalysts for oxygen reduction reaction (ORR) at room temperature

Blocking Behavior of Covalently Attached Anthraquinone Towards Solution‐Based Redox Probes

Contact Info

Product

Resources

About