Oxygen vacancy boosted photocatalytic decomposition of ciprofloxacin over Bi2MoO6: Oxygen vacancy engineering, biotoxicity evaluation and mechanism study

Tailoring Oxygen Vacancies in CoMoO4 for Superior Lithium Storage

“…[31] Furthermore, the peak of CoMoO 4 -N 2 is the sharpest and strongest, confirming the highest concentration of oxygen vacancies in CoMoO 4 -N 2 . The detailed oxygen vacancy concentration was calculated based on the EPR peak areas, [32,33] and the 2, 2, 6, 6-Tetramethylpiperidinooxy was used as the standard sample. The oxygen vacancy concentration in CoMoO 4 -N 2 , CoMoO 4 -Air, and CoMoO 4 -Precursor is 4.14 × 10 15 , 1.04 × 10 15 , and 2.74 × 10 15 spins/cm 3 , respectively.…”

Recent advances in photodegradation of antibiotic residues in water

“… Strategies Catalysts and concentration Light source Antibiotic and concentration Degradation efficiency Ref. Vacancies BiOCl with abundant oxygen vacancies 0.5 g/L 300-W Xe lamp (λ > 420 nm) Tetracycline hydrochloride 10 mg/L Approximately 87% optimum within 2 h [51] Vacancies Oxygen vacancy-rich mesoporous ZrO 2 1 g/L 300-W Xe lamp (λ > 420 nm) Tetracycline hydrochloride 40 mg/L Approximately 80% optimum within 150 h [52] Vacancies BiOBr microspheres with oxygen vacancies 1 g/L 10-W LED lamp (0.4 mW‧cm −2 ) Tetracycline (TC) 20 mg/L Approximately 94% optimum within 90 min [53] Vacancies ZnWO 4-x nanorods with oxygen vacancy 0.2 g/L Hg lamp 300-W UV or 300-W Xe lamp (UV–Vis-NIR) Tetracycline 20 mg/L Approximately 91% optimum within 90 min [54] Vacancies Bi 2 MoO 6 with oxygen vacancy 0.4 g/L 300-W Xe lamp (λ > 400 nm) Ciprofloxacin 20 mg/L Approximately 55% optimum within 120 min [55] Doping Carbon-doped g-C 3 N 4 0.5 g/L Sunlight Tetracycline 20 mg/L Approximately 90% optimum within 90 min [56] Doping P-O co-doped g-C 3 N 4 1 g/L 350-W Xe lamp (λ>420 nm) Enrofloxacin10 mg/L Approximately 90% within 80 min [57] Doping I and K co-doped g-C 3 N 4 2 g/L 300-W Xe lamp (λ>420 nm) Sulfamethoxazole 10 mg/L Approximately 99% optimum within 45 min [58] …”

Enhanced photodegradation of decabromodiphenyl ether on oxygen vacancy-enriched Bi2MoO6

“…Via the modulation of tetramethylethylenediamine (TMEDA) in solvothermal process, oxygen vacancies can be tunably introduced into Bi 2 MoO 6 crystal lattice, which has been successfully applied in the photocatalytic oxidative degradation of ciprofloxacin. 27 …”