In the current paper, we introduce new subclasses of analytic and bi-univalent functions involving Caputo-type fractional derivatives subordinating to the Lucas polynomial. Furthermore, we find non-sharp estimates on the first two Taylor–Maclaurin coefficients a2 and a3 for functions in these subclasses. Using the values of a2 and a3, we determined Fekete–Szegő inequality for functions in these subclasses. Moreover, we pointed out some more subclasses by fixing the parameters involved in Lucas polynomial and stated the estimates and Fekete–Szegő inequality results without proof.