Amorphous indium-gallium-zinc
oxide (a-IGZO) films, which are widely
regarded as a promising material for the channel layer in thin-film
transistors (TFTs), require a relatively high thermal annealing temperature
to achieve switching characteristics through the formation of metal–oxygen
(M–O) bonding (i.e., the activation process). The activation
process is usually carried out at a temperature above 300 °C;
however, achieving activation at lower temperatures is essential for
realizing flexible display technologies. Here, a facile, low-cost,
and novel technique using cellophane tape for the activation of a-IGZO
films at a low annealing temperature is reported. In terms of mechanochemistry,
mechanical pulling of the cellophane tape induces reactive radicals
on the a-IGZO film surface, which can give rise to improvements in
the properties of the a-IGZO films, leading to an increase in the
number of M–O bonds and the carrier concentration via radical
reactions, even at 200 °C. As a result, the a-IGZO TFTs, compared
to conventionally annealed a-IGZO TFTs, exhibited improved electrical
performances, such as mobility, on/off current ratio, and threshold
voltage shift (under positive bias temperature and negative bias temperature
stress for 10,000 s at 50 °C) from 8.25 to 12.81 cm2/(V·s), 2.85 × 107 to 1.21 × 108, 6.81 to 3.24 V, and −6.68 to −4.93 V, respectively.