p-Vinylacetophenone: The Disproportionation of p-Acetophenylmethylcarbinol<sup>1</sup>

Williams, J. L. R.

doi:10.1021/ja01107a520

Cited by 10 publications

(11 citation statements)

References 2 publications

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“…Reports on the crystal structure of the cementitious compound 12CaO'7AlzO3 have appeared previously (Btissem & Eitel, 1936;Jeevaratnam, Dent Glasser & Glasser, 1962;Bartl, 1969) and the structure of the fluoride analogue of the monohydrate has also been reported (Williams, 1968(Williams, , 1969. This communication details the results of further refinement of the latter structure.…”

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confidence: 57%

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Refinement of the structure of 11CaO.7Al₂O₃.CaF₂

Williams¹

1973

Acta Crystallogr B Struct Sci

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confidence: 57%

“…The material used for the study, the data collection procedures, and an approximate structure have been previously described (Williams, 1968(Williams, , 1969 (1962).…”

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confidence: 99%

Refinement of the structure of 11CaO.7Al₂O₃.CaF₂

Williams¹

1973

Acta Crystallogr B Struct Sci

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“…On further oxidation to the Ru III Ru III species, [ 1 ] 2+ , a new intense transition appeared at 808 nm (ε = 22 950 M -1 cm -1 ) which is assigned to a ligand → Ru III LMCT transition involving the bridging ligand bpytz and/or the terminal acac ligands …”

Section: Resultsmentioning

confidence: 99%

Isovalent and Mixed-Valent Diruthenium Complexes [(acac)₂Ru^II(μ-bpytz)Ru^II(acac)₂] and [(acac)₂Ru^II(μ-bpytz)Ru^III(acac)₂](ClO₄) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation

et al. 2004

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The title compounds involving the structurally characterized bridging ligand bpytz were characterized, showing very strong electrochemical stabilization of the mixed-valent RuIIRuIII state (Kc = 10(13.9)) but no detectable (epsilon < 20 M(-1) cm(-1)) intervalence charge-transfer band in the infrared region. In situ reduction of the neutral precursor produces a diruthenium(II) complex of the bpytz radical anion according to EPR spectroscopy, whereas oxidation of the mixed-valent form leads to a diruthenium(III) species.

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“…Two oximes were isolated from (a), by differential solubility in hexane, but only the less soluble dinitrophenylhydrazorie was isolated. Only unsaturated derivatives were isolated from (6).…”

Section: Pyrolysis Of Polyvinylacetophenone and Identification Of mentioning

confidence: 99%

Polyvinylacetophenone: Preparation, reactions, and depolymerization

Kenyon

Waugh

1958

J. Polym. Sci.

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Polyvinylacetophenone was made by the Friedel‐Crafts reaction of acetyl chloride or acetyl bromide on polystyrene, in carbon disulfide, using aluminum chloride. Similar reactions, using bromoacetyl bromide or chloroacetyl chloride, gave insoluble polyvinylphenacyl halides. A soluble, low‐molecular‐weight polyvinylphenacyl chloride was obtained using chloroacetyl chloride and monomeric styrene. Polyvinylphenacyl bromides of limited Solubility were obtained by direct bromination of polyvinylacetophenone. Vacuum pyrolysis of polyvinylacetophenone gave p‐vinylacetophenone monomer in good yield. At atmospheric pressure, the product was about half p‐vinylacetophenone and half p‐ethylacetophenone. At intermediate pressure, an intermediate proportion was obtained.

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p-Vinylacetophenone: The Disproportionation of p-Acetophenylmethylcarbinol¹

Cited by 10 publications

References 2 publications

Refinement of the structure of 11CaO.7Al₂O₃.CaF₂

Refinement of the structure of 11CaO.7Al₂O₃.CaF₂

Isovalent and Mixed-Valent Diruthenium Complexes [(acac)₂Ru^II(μ-bpytz)Ru^II(acac)₂] and [(acac)₂Ru^II(μ-bpytz)Ru^III(acac)₂](ClO₄) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation

Polyvinylacetophenone: Preparation, reactions, and depolymerization

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p-Vinylacetophenone: The Disproportionation of p-Acetophenylmethylcarbinol1

Cited by 10 publications

References 2 publications

Refinement of the structure of 11CaO.7Al2O3.CaF2

Refinement of the structure of 11CaO.7Al2O3.CaF2

Isovalent and Mixed-Valent Diruthenium Complexes [(acac)2RuII(μ-bpytz)RuII(acac)2] and [(acac)2RuII(μ-bpytz)RuIII(acac)2](ClO4) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation

Polyvinylacetophenone: Preparation, reactions, and depolymerization

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p-Vinylacetophenone: The Disproportionation of p-Acetophenylmethylcarbinol¹

Refinement of the structure of 11CaO.7Al₂O₃.CaF₂

Refinement of the structure of 11CaO.7Al₂O₃.CaF₂

Isovalent and Mixed-Valent Diruthenium Complexes [(acac)₂Ru^II(μ-bpytz)Ru^II(acac)₂] and [(acac)₂Ru^II(μ-bpytz)Ru^III(acac)₂](ClO₄) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR Investigation