“…Since the discovery of photo-electrochemical splitting of water on TiO 2 [1], TiO 2 photocatalyst has received special attention as a promising photocatalytic semiconductor. Moreover, TiO 2 has been widely studied both experimentally and theoretically because of its excellent functionality, long-term stability, nontoxicity, wide band gap, unique optical and electronic properties, and low cost [2,3]. Specially, anatase structure has been proven to be the most promising photovoltaic solar cells and photocatalysis [4].…”