The Highland Boundary fault near Stonehaven, NE Scotland, provides a rare opportunity to study the internal fault structure of a well-exposed, along-strike section of an ancient plate boundary fault. As in many plate boundaries, serpentinite juxtaposes quartzo-feldspathic crustal rocks of distinct terranes. We report, for the first time, the complex internal structure of the Highland Boundary fault core, comprised of four structurally and chemically distinct clay-rich units that remain unmixed. Despite the evidence for internal strain, relatively intact clasts of wall rock and microfossils are preserved within the clay. The fault core clay minerology is consistent with a shallow, low temperature authigenesis derived from shearenhanced chemical reactions between wall rocks of contrasting chemistry during sinistral strike-slip. The observed structure is comparable to those of other major weak-cored plate boundaries (e.g., San Andreas fault). Through detailed mapping, we demonstrate that the internal structure of a plate boundary fault core can vary in thickness and composition along-strike over centimetre to meter length scales. 2 Earthquake rupture mechanics critically depend on the physical properties of fault rock assemblages. Therefore, models that investigate rupture propagation at active plate boundaries should incorporate, or else assess tolerance and sensitivity to, variable fault core thickness and composition. SUPPLEMENTARY MATERIAL: Further X-ray diffraction (XRD) analytical data are available at https://doi.org/xxxx'. 3 Understanding the internal structure of large faults is crucial because the chemical and mechanical properties of faults control how earthquakes rupture, nucleate and propagate (e.g., Caine et al. 1996; Wibberley et al. 2008; Faulkner et al. 2010). Geologists studying faults exhumed from depth have shown that they are heterogeneous along-strike and down-dip at a variety of scales (Faulkner et al. 2003;