The particle attrition could lead to the degradation of industrial product quality and results in a series of environmental problems. However, the influence of material properties on the attrition process of particles has long been ignored by researchers. In this article, the particle attrition characteristics of inorganic materials are investigated in a laboratory-scale fluidized bed reactor (FBR). This research is focused on the attrition behavior of particle in FBR. On the other hand, the influence of attrition time, circulation flow rate, and attrition propensity on particle attrition is also studied by using the attrition kinetic model. The experiment results of particle size distribution indicate that the particle attrition in the FBR arises from surface abrasion. Meanwhile, it is found that the attrition rate decline slows and approaches a constant value with increasing attrition time. In addition, the attrition rate increases with circulation flow rate and attrition propensity. It can be seen that the attrition process of particle is strongly related to its material physical characteristics and fluidization conditions. However, the widely used Gwyn's model cannot accurately describe these characteristics. In the current study, a new model of abrasion attrition theory coupled with material mechanical characteristics of particle is implemented to describe the attrition process. The model parameters have definite meanings and are highly correlated with the material mechanical properties of particle, and the predictions of this new coupled model are also in better agreement with Gwyn's model.