“…[2][3][4]27,[30][31][32][33][34][35][36] The onset of flow instability in a fluidized bed, 37 which is associated with a transition from the particulate/homogeneous fluidization to aggregative/heterogeneous fluidization, and the determination of the minimum bubbling velocity (especially for fine particles belonging to Geldart group A), is notoriously hard to predict. 36,38,39 With changes in operating conditions (e.g., the gas velocity and solids flux) and material properties, the flow instability further develops such that a homogeneous suspension gives way to various heterogeneous, mesoscale structures in terms of, for example, bubbles, clusters, and vortices, 2,8,[40][41][42][43][44][45][46][47] where Kn ε and Kn T could be large besides large Kn U . 8 For example, in a moderately dense fluidization regime, say that of a bubbling fluidized bed, the flow is dominated by binary particle collisions where the particle velocity distribution is nearly Maxwellian in both the dense emulsion and dilute bubbles but is much skewed from the Maxwellian distribution and is even bimodal over the interface of bubbles/ clusters.…”