Crystallographic studies of Bismuth (Bi) layer structured ferroelectric (BLSF) materials were first carried out by Aurivillius [1][2][3] and their ferroelectric or piezoelectric properties have been revealed by a large number of researchers [4-106, 108, 110-117] [39,53,63] ceramic materials have been reported in terms of resonator application. Their applicability to practical application seemed to be quite high because the electromechanical coupling factors for thickness extensional mode vibrations were between 15 and 20%, and the typical values for the mechanical quality factor (Q m ) were higher than 2,000 [39], and these properties are favorable for the oscillator applications. However, their temperature coefficient of resonance frequency (TCF) is not sufficiently low for the oscillator applications which require a stable resonance frequency with fine tolerance against various condition changes such as temperature changes.Ando and coresearchers have studied the resonance characteristics of the BLSF materials, and reported that SrBi 2 Nb 2 O 9 (SBN) ceramic material has small TCF values and can be used in the fine tolerance oscillator applications [38,44,72,73,[84][85][86]89]. Single mode resonant characteristics were also successfully obtained for the second harmonic of the thickness extensional (TE2) mode generated by a double-layered resonator structure with SBN material [38,84]. Moreover, a highly stable resonator characteristic at high temperatures is expected for the SBN since its measured Curie temperature was around 400 C [38,44,72,85], which is higher than that of typical lead containing materials such as PZT-or PbTiO3-based ceramics.