While centralized query processing over collections of XML data stored at a single site is a well understood problem, centralized query evaluation techniques are inherently limited in their scalability when presented with large collections (or a single, large document) and heavy query workloads. In the context of relational query processing, similar scalability challenges have been overcome by partitioning data collections, distributing them across the sites of a distributed system, and then evaluating queries in a distributed fashion, usually in a way that ensures locality between (sub-)queries and their relevant data. This thesis presents a suite of query evaluation techniques for XML data that follow a similar approach to address the scalability problems encountered by XML query evaluation.Due to the significant differences in data and query models between relational and XML query processing, it is not possible to directly apply distributed query evaluation techniques designed for relational data to the XML scenario. Instead, new distributed query evaluation techniques need to be developed. Thus, in this thesis, an end-to-end solution to the scalability problems encountered by XML query processing is proposed.Based on a data partitioning model that supports both horizontal and vertical fragmentation steps (or any combination of the two), XML collections are fragmented and distributed across the sites of a distributed system. Then, a suite of distributed query evaluation strategies is proposed. These query evaluation techniques ensure locality between each fragment of the collection and the parts of the query corresponding to the data in this fragment. Special attention is paid to scalability and query performance, which is achieved by ensuring a high degree of parallelism during distributed query evaluation and by avoiding access to irrelevant portions of the data.For maximum flexibility, the suite of distributed query evaluation techniques proposed in this thesis provides several alternative approaches for evaluating a given query over a given distributed collection. Thus, to achieve the best performance, it is necessary to predict and compare the expected performance of each of these alternatives. In this work, this is accomplished through a query optimization technique based on a distribution-aware cost model. The same cost model is also used to fine-tune the way a collection is fragmented to the demands of the query workload evaluated over this collection. v To evaluate the performance impact of the distributed query evaluation techniques proposed in this thesis, the techniques were implemented within a production-quality XML database system. Based on this implementation, a thorough experimental evaluation was performed. The results of this evaluation confirm that the distributed query evaluation techniques introduced here lead to significant improvements in query performance and scalability both when compared to centralized techniques and when compared to existing distributed query evaluation tec...